Recent advances in core-shell organic framework-based photocatalysts for energy conversion and environmental remediation

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外文摘要：Direct conversion of solar energy into chemical energy in an environmentally friendly manner is one of the most promising strategies to deal with the environmental pollution and energy crisis.Among a variety of materials developed as photocatalysts,the core-shell metal/covalent-organic framework(MOF or COF)photocatalysts have garnered significant attention due to their highly porous structure and the adjustabil-ity in both structure and functionality.The existing reviews on core-shell organic framework photocat-alytic materials have mainly focused on core-shell MOF materials.However,there is still a lack of in-depth reviews specifically addressing the photocatalytic performance of core-shell COFs and MOFs@COFs.Simultaneously,there is an urgent need for a comprehensive review encompassing these three types of core-shell structures.Based on this,this review aims to provide a comprehensive under-standing and useful guidelines for the exploration of suitable core-shell organic framework photocatalysts towards appropriate photocatalytic energy conversion and environmental governance.Firstly,the classi-fication,synthesis,formation mechanisms,and reasonable regulation of core-shell organic framework were summarized.Then,the photocatalytic applications of these three kinds of core-shell structures in dif-ferent areas,such as H2 evolution,CO2 reduction,and pollutants degradation are emphasized.Finally,the main challenges and development prospects of core-shell organic framework photocatalysts were intro-duced.This review aims to provide insights into the development of a novel generation of efficient and stable core-shell organic framework materials for energy conversion and environmental remediation.

外文关键词：

Organic frameworkCore-shell structurePhotocatalysisEnergy conversionEnvironmental remediation

作者：

Qibing Dong、Ximing Li、Yanyan Duan、Qingyun Tian、Xinxin Liang、Yiyin Zhu、Lin Tian、Junjun Wang、Atif Sial、Yongqian Cui、Ke Zhao、Chuanyi Wang

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作者单位：

School of Environmental Science and Engineering,Shaanxi University of Science and Technology,Xi'an 710021,Shaanxi,China

Guangdong Engineering Technology Research Center for Environmental Purification and Functional Materials,Guangzhou Institute of Industrial Intelligence,Guangzhou 511400,Guangdong,China

Helmholtz-Zentrum Berlin für Materialien und Energie,Kekuléstraβe 5,12489 Berlin,Germany

Jiangxi Key Lab of Flexible Electronics,Flexible Electronics Innovation Institute,Jiangxi Science and Technology Normal University,Nanchang 330013,Jiangxi,China

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基金：

National Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaSAFEA of China("Belt and Road"Innovative Talent Exchange Foreign Expert Project)SAFEA of China(Highend Foreign Expert Project)Alexandervon-Humboldt Foundation of Germany(Group-Linkage Program)

项目编号：

52161145409219761162023041004LG2023041021L

出版年：

2024

DOI：

10.1016/j.jechem.2024.03.042

能源化学

中国科学院大连化学物理研究所中国科学院成都有机化学研究所

能源化学

CSTPCDEI

影响因子：0.654

ISSN：2095-4956

年,卷(期)：2024.95(8)