首页|A comprehensive review on the resynthesis of ternary cathode active materials from the leachate of Li-ion batteries

A comprehensive review on the resynthesis of ternary cathode active materials from the leachate of Li-ion batteries

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This review highlights the importance of recovering valuable metals from spent Li-ion battery(LIB)cath-odes through the resynthesis of cathode active materials(CAMs).The resynthesis process of CAMs,a promising recycling method that directly produces CAM precursors from LIB leachate,is explored.This process encompasses six key steps,including pretreatment,leaching,purification,adjustment of metal concentrations,precursor synthesis,and sintering.The review also investigates the potential introduction of impurity elements during CAM resynthesis and provides tolerance levels for these impurities based on thorough reference analysis.Additionally,it addresses challenges related to the commercialization of the resynthesis process.Notably,this review represents the first comprehensive assessment of CAM resyn-thesis,including the systematic evaluation of 12 impurity elements(Fe,Li,Al,Cu,C,P,F,Na,Cl,S,Mg,and Zn).Overall,this comprehensive review is poised to support the commercial development of resyn-thesized CAMs by offering valuable guidelines for managing impurities and streamlining the purification process.

Li-ion batteryRecyclingResynthesisLeachateImpurity

Dongwoo Kim、Hyeoncheol Joo、Chanmin Kim、Seoa Kim、Wan-Yi Kim、Sangwoo Han、Joongkil Park、Soyeon Park、Heechul Jung、Sanghyuk Park、Kyungjung Kwon

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Department of Energy and Mineral Resources Engineering,Sejong University,Seoul 05006,Republic of Korea

LIB Recycling Research Group,LIB Materials R&D Center,POSCO Holdings,Pohang 37859,Republic of Korea

Department of Future Energy Convergence,Seoul National University of Science & Technology,232 Gongreung-ro,Nowon-gu,Seoul 01811,Republic of Korea

Autonomous Intelligent Unmanned Flying Vehicles Institute,Sejong University,Seoul 05006,Republic of Korea

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National Research Foundation of Korea(NRF)grant funded by the Korea government(Ministry of Science and ICT)Ministry of Education

RS-2023-002544242020R1A6A1A03038540

2024

能源化学
中国科学院大连化学物理研究所 中国科学院成都有机化学研究所

能源化学

CSTPCDEI
影响因子:0.654
ISSN:2095-4956
年,卷(期):2024.95(8)