首页|Implications of electrode modifications in aqueous organic redox flow batteries
Implications of electrode modifications in aqueous organic redox flow batteries
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Aqueous organic redox flow batteries(RFBs)exhibit favorable characteristics,such as tunability,multi-electron transfer capability,and stability of the redox active molecules utilized as anolytes and catho-lytes,making them very viable contenders for large-scale grid storage applications.Considerable attention has been paid on the development of efficient redox-active molecules and their performance optimization through chemical substitutions at various places on the backbone as part of the pursuit for high-performance RFBs.Despite the fact that electrodes are vital to optimal performance,they have not garnered significant attention.Limited research has been conducted on the effects of electrode mod-ifications to improve the performance of RFBs.The primary emphasis has been given on the impact of electrode engineering to augment the efficiency of aqueous organic RFBs.An overview of electron trans-fer at the electrode-electrolyte interface is provided.The implications of electrode modification on the performance of redox flow batteries,with a particular focus on the anodic and cathodic half-cells sepa-rately,are then discussed.In each section,significant discrepancies surrounding the effects of electrode engineering are thoroughly examined and discussed.Finally,we have presented a comprehensive assess-ment along with our perspectives on the future trajectory.
Redox flow batteriesElectrode modificationOrganic redox moleculesOuter sphere and inner sphere
Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management(IRC-HTCM),King Fahd University of Petroleum & Minerals(KFUPM),Dhahran 31261,Saudi Arabia
Department of Materials Science and Engineering,King Fahd University of Petroleum and Minerals,Dhahran 31261,Saudi Arabia
Interdisciplinary Research Center for Sustainable Energy Systems(IRC-SES),King Fahd University of Petroleum and Minerals,Dhahran 31261,Saudi Arabia
Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management(IRC-HTCM)at King Fahd University of Petroleum