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Sustainable production of high-energy-density jet fuel via cycloaddition reactions

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Developing an energy supply-chain based on renewable biomass holds great potential to build a low car-bon society.High-energy-density(HED)jet fuel,featuring unique fused/strained cycloalkanes,is of great significance for volume-limited military aircrafts,as their high density and combustion heat can extend flight duration and increase the payload.Therefore,the exploration of biomass-based routes towards HED fuel has drawn much attention over the past decade.Cycloaddition reaction features rapid construction of various carbocycles in an atom-and step-economical fashion.This elegant strategy has been widely applied in the manufacture of sustainable HED fuel.Here we carefully summarize the progress achieved in this fascinating area and the review is categorized by the cycloaddition patterns including[4+2],[2+2],[4+4],and[2+1]cycloadditions.Besides,the energy densities of the as-prepared biofuels and petroleum-based fuels(conventional Jet-A and advanced JP-10)are also compared.This review will provide impor-tant insights into rational design of new HED fuel with different ring-types/sizes and inspire the chemists to turn those literature studies into practical applications in military field.

High-energy-density fuelBiomass-based chemicalsCycloadditionCycloalkanesCatalysis

Yan-Cheng Hu、Yingying Zhao、Ning Li、Jing-Pei Cao

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School of Chemical Engineering and Technology,China University of Mining and Technology,Xuzhou 221116,Jiangsu,China

School of Education Science,Jiangsu Normal University,Xuzhou 221116,Jiangsu,China

CAS Key Laboratory of Science and Technology on Applied Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,Liaoning,China

National Key R&D Program of ChinaXuzhou Basic Research ProjectFundamental Research Funds for the Central UniversitiesPriority Academic Program Development of Jiangsu Higher Education Institutions

2022YFB4201802KC230182023-00104

2024

10.1016/j.jechem.2024.04.024

能源化学
中国科学院大连化学物理研究所 中国科学院成都有机化学研究所

能源化学

CSTPCDEI
影响因子：0.654
ISSN：2095-4956
年,卷(期)：2024.95(8)