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杏仁壳生物炭的改性以及性能的研究

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铁基吸附剂作为一种常见的吸附剂,对水环境中的砷具有良好的吸附效果因而受到环境领域的广泛关注.本文将氧化铁载到杏仁壳生物炭上,对生物炭进行改性并研究了活化时间为3 h,煅烧温度为500 ℃,氧化铁负载量为3%的改性杏仁壳生物炭的比表面积及对其吸附性能进行研究,研究结果表明:改性杏仁壳生物炭具有有序的石墨结构,微孔比较发达,吸附性能好;氧化铁晶体嵌入大孔的内壁这使生物炭原有的大孔变成许多小的微孔,降低了生物炭的平均孔径,增大了改性杏仁壳生物炭的吸附性能;采用BET液氮吸附法表征分析活化时间为3 h,煅烧温度为500 ℃,氧化铁负载量为3%的改性杏仁壳生物炭的比表面积为909.75 m2/g,总孔容积0.48 mL/g,微孔容积为0.34 mL/g,平均孔径为4.58 nm.
Research on modification and properties of almond shell biochar
Iron based adsorbents,as a common adsorbent,have good adsorption effects on arsenic in water environments and have received widespread attention in the environmental field.This article describes the modification of almond shell biochar by loading iron oxide onto it,and investigates the specific surface area and adsorption performance of the modified almond shell biochar with an activation time of 3 hours,a calcination temperature of 500 ℃,and an iron oxide loading of 3%.The research results show that the modified almond shell biochar has an ordered graphite structure,well-developed micropores,and good adsorption performance;The embedding of iron oxide crystals into the inner walls of large pores turns the original large pores of biochar into many small micropores,reducing the average pore size of biochar and increasing the adsorption performance of modified almond shell biochar;The BET liquid nitrogen adsorption method was used to characterize and analyze the modified almond shell biochar with an activation time of 3 hours,a calcination temperature of 500 ℃,and a 3%iron oxide loading.The specific surface area was 909.75 m2/g,the total pore volume was 0.48 mUg,the micropore volume was 0.344 mL/g,and the average pore size was 4.58 nm.

iron-based adsorbentbiocharmodification

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七台河矿业公司龙湖煤矿,七台河 154622

铁基吸附剂 生物炭 改性

2024

炭素
哈尔滨电碳研究所 中国电工技术学会碳石墨材料专业委员会

炭素

影响因子:8.75
ISSN:1001-8948
年,卷(期):2024.(2)