首页|煤重质组制备活性炭对亚甲基蓝和苯酚的吸附性能及机理研究

煤重质组制备活性炭对亚甲基蓝和苯酚的吸附性能及机理研究

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以童亭煤重质组族组分为原料,KOH为活化剂,制备了高比表面积活性炭,研究了碱炭比对活性炭孔结构及其吸附亚甲基蓝和苯酚性能的影响.结果表明,活性炭AC-4有最大的比表面积(3 752 m2/g),对2 000 mg/L的亚甲基蓝溶液吸附量达到最大,为1 996.74 mg/g,吸附率高达99.84%;而活性炭AC-2对120 mg/L的苯酚溶液吸附量达到最大,为107.08 mg/g,吸附率高达89.23%.活性炭对亚甲基蓝和苯酚有不同的吸附机制,对亚甲基蓝的吸附以孔隙填充为主,而对苯酚的吸附则以π-π相互作用为主.
Adsorption performance and mechanism of MB and phenol on activated carbon prepared from coal heavy component
High surface area activated carbons were prepared using the heavy components(HC)from Tongting coal as the raw material and KOH as the activating agent.The effects of the KOH/HC mass ratios on the pore structure of the activated carbon and its adsorption performance towards methylene blue and phenol were investigated.The results show that the activated carbon AC-4 exhibites the high-est specific surface area of 3 752 m2/g and a maximum adsorption capacity of 1 996.74 mg/g with a remarkable adsorption rate of 99.84%for a MB solution with an initial concentration of 2 000 mg/L.In contrast,the activated carbon AC-2 demonstrates a maximum adsorption capacity of 107.08 mg/g with a high adsorption rate of 89.23%for a phenol solution with an initial concentration of 120 mg/L.The activated carbon has different adsorption mechanisms for methylene blue and phenol.The adsorption of methylene blue is primarily attributed to pore filling,whereas the adsorption of phenol is mainly governed by π-π interactions.

Activated carbonadsorptioncoal heavy componentmethylene bluephenol

刘志铭、谈胜福、郑苏霞、杨小芹、秦志宏

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中国矿业大学化工学院,江苏徐州 221116

活性炭 吸附 煤重质组 亚甲基蓝 苯酚

国家自然科学基金

21706276

2024

炭素技术
中钢集团吉林炭素股份有限公司

炭素技术

CSTPCD北大核心
影响因子:0.296
ISSN:1001-3741
年,卷(期):2024.43(1)
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