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炭微球改性的丙烯酸酯吸油树脂的制备及其性能研究

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为提升吸油树脂的吸油能力,引入新型炭微球对丙烯酸酯类树脂进行复合改性.以甲基丙烯酸异辛酯(EHMA)、聚丙烯酸十八烷基酯(SMA)为功能单体,苯乙烯(ST)为刚性单体,同时在悬浮聚合过程中引入炭微球成功制备了复合型吸油树脂.对合成的复合吸油树脂进行结构测试和吸油性能表征.结果表明,复合吸油树脂中炭微球与树脂实现较好的复合,其吸油性能相较于不加炭微球得到明显提升.复合吸油树脂对柴油、煤油、汽油的饱和吸油率分别为 18.214,17.421,5.124 g/g,较未复合吸油树脂分别提升了 17.4%、25.1%、23.2%;对柴油、煤油、汽油的分离率分别为 68.2%、95.6%、96.3%,并且具有良好的循环使用性,具有较好的应用前景.
Preparation and properties of acrylate oil-absorbing resin modified by carbon microspheres
This paper introduces a new type of carbon microsphere for composite modification of acrylic resin to enhance its oil absorp-tion ability.Specifically,the composite oil absorption resin was successfully prepared by using isooctyl methacrylate(EHMA)and octa-decyl polyacrylate(SMA)as functional monomer,styrene(ST)as rigid monomer,and introducing carbon microsphere in the suspen-sion polymerization process.Structure and oil absorption performance of the synthesized composite oil absorption resin were conducted.The results show that the composite oil absorbing resin exhibits a good combination of carbon microsphere and resin,and the oil absorp-tion performance is significantly improved compared to the absence of carbon microsphere.The saturated oil absorption rates of compos-ite oil absorption resin for diesel,kerosene,and gasoline are 18.214,17.421,15.124 g/g,respectively,which are increased by 17.4%,25.1%,and 23.2%,respectively,compared to the oil absorption resin without carbon microsphere.The separation rates for diesel,kero-sene,and gasoline are 68.2%,95.6%,and 96.3%,respectively,which have good recyclability and good application prospects.

Acrylatescarbon microspheresoil-absorbing resinssuspension polymerization

冯硕、刘浩

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中海石油(中国)有限公司 天津分公司工程技术作业中心,天津 300450

中航复合材料有限责任公司,北京 101300

丙烯酸酯 炭微球 吸油树脂 悬浮聚合

2024

炭素技术
中钢集团吉林炭素股份有限公司

炭素技术

CSTPCD北大核心
影响因子:0.296
ISSN:1001-3741
年,卷(期):2024.43(3)