首页|处理温度对粉末-先驱体法制备C/C-ZrC-SiC复合材料的力学性能影响

处理温度对粉末-先驱体法制备C/C-ZrC-SiC复合材料的力学性能影响

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以改性的聚甲基硅烷(PMS)作为硅源,碳化锆作为锆源,采用粉末-先驱体法制备出C/C-ZrC-SiC复合材料.对比C/C-ZrC-SiC复合材料在 1 400,1 600,1 800℃热处理后的微观结构和力学性能变化,从而探究不同热处理温度对C/C-ZrC-SiC复合材料的影响.结果表明,在 1 400℃热处理条件下,SiC-ZrC陶瓷与炭纤维结合保持致密,共同抵抗弯曲形变,制备的C/C-ZrC-SiC复合材料具有 182 MPa的抗弯强度.在 1 600℃和 1 800℃热处理条件下的SiC陶瓷会发生晶型转变而导致结合强度下降,形貌发生变化,表现出较差的力学性能,抗弯强度分别下降至 78 MPa和 65 MPa.
Effect of treatment temperature on mechanical properties of C/C-ZrC-SiC composites prepared by powder-precursor method
C/C-ZrC-SiC composites were prepared by powder-precursor method using modified polymethylsilane(PMS)as silicon source and zirconium carbide as zirconium source.The effects of heat treatment temperatures on the C/C-ZrC-SiC composites were in-vestigated by comparing the changes in microstructure and mechanical properties of the composites after heat treatment at 1 400,1 600,1 800℃.At 1 400℃,the SiC-ZrC ceramics and the carbon fibers remain densely bonded and jointly resist bending deforma-tion,and the prepared C/C-ZrC-SiC composites have a flexural strength of 182 MPa.At 1600℃and 1 800℃,the SiC undergoes a crystalline transition that leads to a change in morphology and a decrease in bond strength,showing poor mechanical properties,with the flexural strength decreasing to 78 MPa and 65 MPa,respectively.

C/C-ZrC-SiC compositesheat treatment temperaturemechanical propertymicrostructure

钟城浩、廖明东、胡协波、沈国波、黄启忠、苏哲安

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中南大学 粉末冶金国家重点实验室,湖南 长沙 430081

C/C-ZrC-SiC复合材料 热处理温度 力学性能 微观结构

2024

炭素技术
中钢集团吉林炭素股份有限公司

炭素技术

CSTPCD北大核心
影响因子:0.296
ISSN:1001-3741
年,卷(期):2024.43(5)