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丝网印刷石墨烯发热膜浆料配比实验研究

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为了研究炭黑、DBE对石墨烯油墨的印刷适性和发热膜导电性的影响,寻找既能增强发热膜导电性又能保持良好印刷适性的最佳配比,本文采用单因素法,在石墨烯原浆中通过添加不同含量的炭黑和DBE制备多组石墨烯电热油墨,并印制石墨烯发热膜.通过测试油墨在不同温度或剪切速率下的黏度、发热膜的方阻、SEM图等探究石墨烯电热油墨的最佳配比.结果表明,随着炭黑含量的增加,油墨黏度变大,方阻先减小后增大,含量为 0.9%时方阻最小.随着DBE含量增加,油墨黏度减小,方阻逐渐增大.添加8%的DBE和1.8%的炭黑配制的油墨具有良好的印刷适性,配合100 目网版印制的发热膜方阻较直接使用原浆减小了 50.4%.同时添加炭黑和DBE是保持印刷适性、降低发热膜方阻的有效方法.
Experimental study on matching ratio of slurry for silkscreen printing graphene heating film
To investigate the impact of carbon black and DBE on the printability of graphene inks and the electrical conductivity of thermal film,and to determine the optimal ratio that enhances electrical conductivity while maintaining good printability,multiple groups of graphene electric heating inks were prepared using a single-factor method by varying amounts of carbon black and DBE to graphene raw slurry.Subsequently,graphene heating films were printed.Through viscosity testing at different temperatures or shear rates,square resistance measurement of the heating film,and SEM imaging analysis,the best ratio for graphene electric heating ink was explored.Results show that as carbon black content increases,ink viscosity also increases;meanwhile,square resistance initially decrea-ses but then increases again.The lowest square resistance is obtained at a carbon black content of 0.9%.On the other hand,with in-creasing DBE content,ink viscosity decreases gradually while square resistance increases.Notably,an ink formulation containing 8%DBE and 1.8%carbon black exhibites excellent printability performance.Furthermore,when printing with a 100 mesh screen compared to direct use of original paste,this formulation resulted in a significant reduction(50.4%)in square resistance for the printed heating film.Simultaneous addition of carbon black and DBE proves to be an effective approach for maintaining printability while reducing ther-mal film resistance.

Graphene inkcarbon blackheating filmviscositysquare resistance

李恒、袁英才、张晋豪、李文浩、龙吉、秦月、蔡红燕

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北京印刷学院 数字化印刷装备北京市重点实验室,北京 102600

北京印刷学院 印刷装备北京市高等学校工程研究中心,北京 102600

北京印刷学院北京市印刷电子工程技术研究中心,北京 102600

北京印刷学院机电工程学院,北京 102600

上海众濒科技有限公司,上海 201400

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石墨烯油墨 炭黑 发热膜 黏度 方阻

2024

炭素技术
中钢集团吉林炭素股份有限公司

炭素技术

CSTPCD北大核心
影响因子:0.296
ISSN:1001-3741
年,卷(期):2024.43(6)