应用海洋学学报2024,Vol.43Issue(2) :315-323.DOI:10.3969/J.ISSN.2095-4972.20230203001

南大洋大气有机胺分布及来源特征研究

Characteristics of atmospheric amine distribution and source over the Southern Ocean

杨航 赵淑惠 林奇 王珊珊 史军 戴思颖 张麋鸣 许苏清 颜金培
应用海洋学学报2024,Vol.43Issue(2) :315-323.DOI:10.3969/J.ISSN.2095-4972.20230203001

南大洋大气有机胺分布及来源特征研究

Characteristics of atmospheric amine distribution and source over the Southern Ocean

杨航 1赵淑惠 2林奇 1王珊珊 1史军 1戴思颖 1张麋鸣 1许苏清 1颜金培1
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作者信息

  • 1. 自然资源部第三海洋研究所,福建厦门 361005;自然资源部海洋大气化学与全球变化重点实验室,福建厦门 361005
  • 2. 泰山学院旅游学院,山东泰安 271000
  • 折叠

摘要

依托中国第36次南极科学考察,利用船载走航气溶胶及气体组分在线分析仪对南大洋大气中气态和颗粒态有机胺进行了在线观测.获得了南大洋开阔海域及普里兹湾大气中高分辨气态和颗粒态有机胺的组成及分布,并对其来源特征进行了分析.结果表明:南大洋大气有机胺以气态三甲胺(TMA)和二甲胺(DMA)为主要存在形态,其均值分别为(104.0±285.2)、(3.5±6.0)ng/m3.普里兹湾大气中有机胺的平均浓度显著高于南大洋开阔海域,气态TMA和DMA均值分别达到(289.0±396.6)、(5.6±16.1)ng/m3.南大洋大气中气态TMA、DMA和氨气(NH3)在不同区域内均具有良好的线性关系,表明三者具有同源性.从来源分析,南大洋大气有机胺主要受到海洋生物活动的影响,但在海冰边缘区及南极近岸海域,企鹅等动物的生物活动会导致大气中有机胺的浓度显著升高.

Abstract

The composition and distribution of atmospheric aerosols and gaseous organic amines over the Southern Ocean and the Antarctic near-shore area were investigated for the first time during the 36Th CHINARE by online ob-servation and their source characteristics were analyzed.Results show that gaseous trimethylamine and dimethyl-amine are the main forms of organic amines in the Southern Ocean,with mean values of(104.0±285.2)and(3.5 ±6.0)ng/m3,respectively.The concentrations of organic amines in the Antarctic near-shore area are significantly higher than the average oceanic concentrations,for example,the mean values of gaseous trimethylamine and dime-thylamine over Prydz Bay reach(289.0±396.6)and(5.6±16.1)ng/m3,respectively.Gaseous trimethylamine,dimethylamine and ammonia over the Southern Ocean showed good linearity in different regions,indicating their ho-mology.From the source analysis,the atmospheric organic amines over the Southern Ocean are mainly influenced by marine biological activities,but in the sea ice edge area and the Antarctic near-shore area,animal activities such as penguin emissions can lead to a significant increase in the concentration of organic amines in the atmos-phere.

关键词

海洋化学/海洋气溶胶/有机胺/南大洋

Key words

marine chemistry/marine aerosol/alkylamine/Southern Ocean

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基金项目

国家自然科学基金(41941014)

自然资源部第三海洋研究所基本科研业务费(海三科2019024)

出版年

2024
应用海洋学学报
国家海洋局第三海洋研究所 中国海洋学会 福建省海洋学会

应用海洋学学报

CSTPCDCSCD北大核心
影响因子:0.526
ISSN:2095-4972
参考文献量33
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