首页|基于中红外腔衰荡光谱的CO2检测系统研制

基于中红外腔衰荡光谱的CO2检测系统研制

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14C是核反应放射性流出物中最受关注的放射性核素之一,核设施产生的14C主要与CO2 标记,因此对14CO2 气体进行在线检测具有重要意义。本研究采用腔衰荡光谱技术(CRDS),以CO2 为研究对象,选取14CO2 吸收谱线的中心波长 2209。11 cm-1 附近检测14CO2 的吸收光谱。采用中红外波段量子级联激光器、光学谐振腔、合理的光路设计和气体管路设计,研制基于中红外腔衰荡光谱的CO2 检测系统。并采用研制的系统检测不同浓度的CO2(0。5%~1。3%)进行验证。结果表明,待测气体浓度与衰荡时间的倒数之间呈线性相关,证实研制的中红外腔衰荡光谱系统可行。该系统成功实现了对不同浓度CO2 气体在中红外波段下的精准测量,使用中红外腔衰荡技术测量得到14CO2 的吸收光谱。为未来激光光谱快速原位检测14CO2 研究提供了重要的技术支持。
Development of Carbon Dioxide Detection Device Based on Mid-Infrared Cavity Decay Spectroscopy Technology
With the rapid development of the nuclear industry,the amount of waste to be treated and monitored increases,and the potential emissions will also increase,and C-14 needs to be monitored.C-14 produced by nuclear facilities is mainly combined with CO2,so sensitive monitoring of 14CO2 gas is of great significance.In this paper,cavity ring-down spectroscopy(CRDS)is used to detect the CO2 absorption spectrum by selecting the center wave number of 14CO2 absorption line around 2209.11 cm-1.A CO2 detection system based on mid-infrared cavity ring-down spectroscopy is developed by using a quantum cascade laser in mid-infrared band,an optical resonator,and a reasonable optical path design and gas pipeline design.Based on the developed system,different concentrations of CO2(0.5%-1.3%)were detected,and the experimental data were fitted and analyzed,and the results were found to be consistent with the theoretical formula,which confirmed the feasibility of the developed mid-infrared cavity ring-down spectrum system.The system has successfully realized the accurate measurement of different concentrations of CO2 gas in the mid-infrared band,the absorption spectrum of 14CO2 was measured by mid-infrared cavity ring-down technique,which provides an important technical support and foundation for the future study of laser spectral detection of 14CO2.

mid-infraredcavity ring-down spectroscopyCO2 gas detectiongas analyser development

张俊博、毛娜请、徐利军、罗瑞、李元桥、来居翰、刘蕴韬

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中国原子能科学研究院,北京 102413

中红外 腔衰荡光谱技术 气体检测系统研制 CO2气体检测

中核集团"青年英才"项目

2024

同位素
中国核学会同位素分会

同位素

CSTPCD
影响因子:0.405
ISSN:1000-7512
年,卷(期):2024.37(5)