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炭黑的微观结构及其在三元乙丙橡胶中的应用性能

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对三种不同工艺方法制备的同一牌号炭黑(N550)进行了微观结构和宏观物理机械性能进行研究.采用扫描电子显微镜(SEM)、透射电子显微镜(TEM)等检测方式,分析三种炭黑聚集体在结构和粒径分布等微观结构上的区别.对比了三种炭黑的微观结构及应用过程中分散状态的差异,并且探究了其在三元乙丙橡胶(EPDM)中物理机械性能和制品加工性能的差别.结果表明,炭黑粒径小,原生粒子之间黏连程度低,炭黑的分散性、补强效果更优,胶料的流动性好,在加工过程中能耗低.
Microstructure of carbon black and its application in EPDM rubber
This paper examines the microstructure and macroscopic physical and mechanical properties of carbon black of the same grade(N550)that is produced using three different processes.The study uses scanning electron microscopy(SEM)and transmission electron microscopy(TEM)to analyze the microstructure and particle size distribution of three kinds of carbon black aggregates.The study compares the differences in microstructure and dispersion state of the three types of carbon black;and investigates the variations in physical and mechanical properties in EPDM and processing properties of products.The research results indicate that carbon black with smaller particle size has lower degree of adhesion between primary particles,better dispersion and reinforcing effect,good fluidity of rubber material,and lower energy consumption during processing.

carbon blackmicrostructureethylene-propylene diene monomerphysical and mechanical propertiysdispersibilityreinforcing effect

李慧、胡琪、顾兆磊、刘显贞、陈琪

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青岛科技大学高分子科学与工程学院橡塑材料与工程教育部重点实验室,山东青岛 266042

江西黑猫炭黑股份有限公司,江西景德镇 333000

炭黑 微观结构 三元乙丙橡胶 物理机械性能 分散性 补强效果

国家重点研发计划项目

2022YFD2301202

2024

弹性体
中国石油天然气股份有限公司吉林石化公司 全国合成橡胶信息总站

弹性体

CSTPCD
影响因子:0.463
ISSN:1005-3174
年,卷(期):2024.34(2)