弹性体2024,Vol.34Issue(5) :60-65.

山梨酸锌/炭黑纳米复合填料对氢化丁腈橡胶的增强作用

Enhancement of hydrogenated nitrile rubber by zinc sorbate/carbon black nanocomposite fillers

薛奥楠 刘大晨 朱博聪 肖小坤
弹性体2024,Vol.34Issue(5) :60-65.

山梨酸锌/炭黑纳米复合填料对氢化丁腈橡胶的增强作用

Enhancement of hydrogenated nitrile rubber by zinc sorbate/carbon black nanocomposite fillers

薛奥楠 1刘大晨 1朱博聪 1肖小坤1
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作者信息

  • 1. 沈阳化工大学材料科学与工程学院,辽宁沈阳 110142
  • 折叠

摘要

采用原位法制备了山梨酸锌(ZDS)并与炭黑(CB)组成纳米复合填料协同补强了氢化丁腈橡胶(HNBR).研究了纳米复合补强HNBR的硫化特性、力学性能、交联密度等,并探讨了 CB/ZDS并用体系的增强机理.结果表明,原位法生成ZDS与橡胶分子链形成离子键合,与CB协同作用可大幅提升HNBR的力学性能,当CB/ZDS质量比为20/30时,硫化胶整体性能最佳,此时拉伸强度可达37.6 MPa,断裂伸长率为376%.

Abstract

Zinc sorbate and carbon black were prepared in situ and used to form a nanocomposite filler to reinforce hydrogenated nitrile rubber(HNBR).The vulcanization characteristics,mechanical properties and crosslink density of the nanocomposites were investigated,and the enhancement mechanism of the two systems was also discussed.The results showed that the in situ generation of zinc sorbate formed ionic bonding with the rubber molecular chain,and the synergistic effect with carbon black could greatly improve the mechanical properties of HNBR.The overall performance of the vulcanized rubber was the best when the dosage of carbon black was 20 and the generation of zinc sorbate was 30,at which the tensile strength could be up to 37.6 MPa,and the elongation at break was 376%.

关键词

氢化丁腈橡胶/山梨酸锌/纳米复合填料/离子键合

Key words

hydrogenated nitrile rubber/zinc sorbate/nanocomposite filler/ionic bonds

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出版年

2024
弹性体
中国石油天然气股份有限公司吉林石化公司 全国合成橡胶信息总站

弹性体

CSTPCD
影响因子:0.463
ISSN:1005-3174
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