太原理工大学学报2025,Vol.56Issue(1) :44-53.DOI:10.16355/j.tyut.1007-9432.20240134

粉煤灰作为土壤改良剂吸附黄土高原红黏土中的磷

Coal Fly Ash as a Soil Amendment for Phosphorus Adsorption in Red Clay Soils of the Loess Plateau

高江奇 段润斌 逯新宇 李育珍 孙曜 朱冰姿
太原理工大学学报2025,Vol.56Issue(1) :44-53.DOI:10.16355/j.tyut.1007-9432.20240134

粉煤灰作为土壤改良剂吸附黄土高原红黏土中的磷

Coal Fly Ash as a Soil Amendment for Phosphorus Adsorption in Red Clay Soils of the Loess Plateau

高江奇 1段润斌 1逯新宇 1李育珍 1孙曜 1朱冰姿1
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作者信息

  • 1. 太原理工大学 环境科学与工程学院,山西 太原
  • 折叠

摘要

[目的]为应对黄土高原及类似环境敏感地区的土壤磷污染,开发粉煤灰回用技术.[方法]通过批处理实验,将粉煤灰作为改良剂,系统研究投加量、pH、初始磷浓度、时间和温度对不同比例粉煤灰改良的红黏土吸附磷的影响.[结果]吸附等温模型、动力学模型及热力学分析结果表明,粉煤灰的添加显著提高了红黏土对磷吸附的最大容量,加快了红黏土磷吸附反应速率并改变了吸附动力学机理,提高了吸附过程的自发性.该研究为解决黄土高原红黏土磷污染与粉煤灰可持续处置问题提供了新思路.

Abstract

[Purposes]This work has been done to deal with soil phosphorus pollution in the Loess Plateau area and similar environmentally sensitive regions and develop a technique for reusing coal fly ash.[Methods]Batch studies with coal fly ash as a soil amendment were conducted to sys-tematically investigate the impact of dosage,pH,initial phosphorus concentration,time,and tempera-ture on phosphorus adsorption in red clay soils with amendment of coal fly ash.[Findings]Isother-mal,kinetic,and thermodynamic analyses indicated that the addition of coal fly ash significantly en-hanced the maximum adsorption capacity of red clay soils for phosphorus,accelerated the adsorption reaction rate,altered the phosphorus adsorption kinetics,and enhanced the spontaneity of the adsorp-tion process.This study provides new insights into addressing phosphorus pollution in red clay soils in the Loess Plateau area and the sustainable disposal of coal fly ash.

关键词

吸附模型/吸附性能/黏土矿物/黄土/Weber-Morris模型

Key words

adsorption models/adsorption performance/clay minerals/loess soils/Weber and Morris model

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出版年

2025
太原理工大学学报
太原理工大学

太原理工大学学报

北大核心
影响因子:0.476
ISSN:1007-9432
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