首页|CuO/Cu4O3@C复合材料在电催化还原CO2中的性能研究

CuO/Cu4O3@C复合材料在电催化还原CO2中的性能研究

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[目的]电催化CO2还原反应(CO2RR)为高价值的化学品目前广受关注。为了提高电催化活性和选择性,制备具有优异CO2RR性能的催化剂十分必要。[方法]选用麦麸为原料制成生物质炭(C),进一步采用简单的水热法制备生物质炭耦合铜氧化物复合电催化剂,并对其进行物化表征和电化学性能测试。[结果]结果显示,在-1。08 V(vs。RHE)的电压下,样品CuO/Cu4O3@C-2在饱和CO2 的0。5 mol/L KHCO3 溶液中,C2H4 的法拉第效率最大(46。32%)。另外在-1。08 V(vs。RHE)时进行了11。5 h的CO2RR稳定性测试,该样品同样展现了优异的稳定性。[结论]研究结果为合成CO2RR成本低廉、高电化学性能的催化剂提供了一种可行的策略。
Performance Study of CuO/Cu4O3@C Composites in Electrocatalytic Reduction of CO2
[Purposes]Electrochemical CO2 reduction reaction(CO2RR)to high-value chemicals is currently receiving widespread attention.In order to improve the electrocatalytic activity and selec-tivity,it is necessary to prepare catalysts with superior CO2RR properties.[Methods]In this study,wheat bran-based biochar(C)was prepared and coupled with copper oxide to get composite electro-catalysts through a simple hydrothermal method,and physicochemical characterizations and electro-chemical performance testings were further condueted.[Findings]The results suggest that the CuO/Cu4O3@C-2 shows the best Faradaic efficiency of C2H4(46.32%)at-1.08 V(vs.RHE).Meanwhile,the sample displays excellent stability for 11.5 h at-1.08 V(vs.RHE).[Conclusions]This study pro-vides a feasible strategy for the synthesis of cost-effective catalysts with high electrochemical perfor-mance.

copper oxidebiocharelectrocatalytic reductioncarbon dioxideethylene

张金男、郭天宇、祁彧、王红涛

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太原理工大学 环境科学与工程学院,山西 晋中

铜氧化物 生物质炭 电催化还原 二氧化碳 乙烯

2025

太原理工大学学报
太原理工大学

太原理工大学学报

北大核心
影响因子:0.476
ISSN:1007-9432
年,卷(期):2025.56(1)