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循环流化床反应器固体生物质的热解液化

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介绍了以循环流化床反应器为主体的固体生物质热解液化装置,实验过程,实验结果及分析。通过对气体产物的比较及油产物一般物性和油成分的分析,得出如下结论:1)较高的温度和较长的停留时间会降低油的产率,生成过多的不凝气;过低的温度和加热速率导致严重的碳化,同样会降低油产率,本实验的最高油产率可达63%。2)生物质热解油品的物性特点主要包括水分含量较高,pH值较低,粘度变化范围很大,热值与化石燃料相比为低,并且油品中因含氧量很高而极不稳定,油品的组成成分非常复杂,烷烃和非烃占据了相当的比例,芳烃和沥青质含量相对较少。3)在循环流化床中的固体生物质热解液化可模化为热解区和还原裂解区。
BIOMASS PYROLYSIS FOR LIQUIDS IN CIRCULATING FLUIDIZED BED(CFB)REACTOR
With the CFB as main reactor,an integrated facility was developed for the fast pyrolysis of biomass.In this facility,the bed is divided into two zones according to the pyrolysis and secondary reactions,the main chemical processes can be modelled.Based on the variation of the pyrolysis gas composition and the bio-oil ingredients,analysis of the experimental data highlights the important effects of temperature,heating rate and residence time.The main trend is that the higher temperature and longer residence time would contribute to the secondary reaction and the lower heating rate favors the carbonization,which both reduce the liquid production.In this study,the best bio-oil yield is 63%in weight.The component analysis of bio-oil shows that most compounds in bio-oil are nonhydrocarbons,while alkanes,aromatics and bitumen are relatively low.The physical properties of bio-oil include the high water and oxygen content,and the low pH and LHV.

戴先文、吴创之、周肇秋、陈勇

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中国科学院广州能源研究所

固体生物质 循环流化床 热解液化

广东省自然科学基金

960421

2001

太阳能学报
中国可再生能源学会

太阳能学报

CSCD北大核心
影响因子:0.392
ISSN:0254-0096
年,卷(期):2001.22(2)
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