首页|药渣木质素定向解聚制备高密度航油合成原料

药渣木质素定向解聚制备高密度航油合成原料

PREPARATION OF FEEDSTOCK FOR HIGH DENSITY JET FUEL SYNTHESIS BY TARGETED DEPOLYMERIZATION OF LIGNIN FROM PHARMACEUTICAL RESIDUES

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以三叉苦药渣木质素为原料,在低共熔溶剂(ChCl-MeOH-AlCl3·6H2O)与催化剂(Cu(OAc)2/邻菲罗啉)耦合作用下解聚生成高密度航油合成原料,考察不同反应温度、时间、固液比、催化剂添加量与氧气含量对木质素催化氧化解聚效果的影响.结果表明:在固液比1∶30 g/mL,木质素、Cu(OAc)2、邻菲罗啉的质量比1∶1∶1,3 MPa氧压,60℃条件下反应3h后,木质素选择性解聚生了芳香醛酮类高密度航油合成原料,木质素转化率达到80.84%,香草乙酮与香草醛收率分别为16.69%和34.39%.
Herein,Lignin from evodia lepta was used as raw material to depolymerize under the coupling of deep eutectic solvent(ChCl-MeOH-AlCl3·6H2O)and catalyst(Cu(OAc)2/1,10-phenanthroline)to generate feedstock for synthesising high-density jet fuel,and the effects of different reaction temperatures,times,solid-liquid ratios,catalyst additions and oxygen pressures on the catalytic oxidative depolymerization of lignin were investigated.The results showed that under the conditions of solid-liquid ratio of 1∶30 g/mL,mass ratio of lignin to Cu(OAc)2 and 1,10-phenanthroline of 1∶1∶1,oxygen pressure of 3 MPa and 60℃for 3 h,the lignin was selectively depolymerized to produce aromatic aldehydes and ketones used as feedstock for synthesizing high-density jet fuel.The lignin conversion rate reached 80.84%,and the yields of acetovanillone and vanillin were 16.69%and 34.39%,respectively.

biomassligninoxidative depolymerizationdeep eutectic solvents

简雅婷、王帆、陈小燕、张宇、余强、袁振宏

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中国科学技术大学工程科学学院,合肥 230026

中国科学院广州能源研究所,中国科学院可再生能源重点实验室,广东省新能源和可再生能源研究开发与应用重点实验室,广州 510640

华南农业大学生物质工程研究院,农业农村部能源植物资源与利用重点实验室,广东省农林生物质工程技术研究中心,广州 510642

生物质 木质素 氧化解聚 低共熔溶剂

国家自然科学基金国家自然科学基金广州市重点研发计划

5187620652276192202103000011

2024

太阳能学报
中国可再生能源学会

太阳能学报

CSTPCD北大核心
影响因子:0.392
ISSN:0254-0096
年,卷(期):2024.45(3)
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