太阳能学报2024,Vol.45Issue(3) :169-177.DOI:10.19912/j.0254-0096.tynxb.2022-1836

密封限氧法制备秸秆生物炭参数的优化研究

OPTIMIZATION STUDY ON PARAMETERS OF STRAW BIOCHAR PREPARED BY SEALED OXYGEN LIMITING METHOD

朱凤君 张春燕 乔印虎 何春霞 辛楠 王宁
太阳能学报2024,Vol.45Issue(3) :169-177.DOI:10.19912/j.0254-0096.tynxb.2022-1836

密封限氧法制备秸秆生物炭参数的优化研究

OPTIMIZATION STUDY ON PARAMETERS OF STRAW BIOCHAR PREPARED BY SEALED OXYGEN LIMITING METHOD

朱凤君 1张春燕 2乔印虎 1何春霞 3辛楠 1王宁1
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作者信息

  • 1. 安徽科技学院机械工程学院,凤阳 233100
  • 2. 安徽科技学院机械工程学院,凤阳 233100;安徽云龙粮机有限公司,阜阳 236500
  • 3. 南京农业大学工学院,南京 210032
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摘要

以小麦秸秆、水稻秸秆和油菜秸秆为原料,利用正交试验思路设计密封限氧处理下制备秸秆生物炭的方案,测定并分析其理化特性、官能团结构及形貌特征.结果表明:炭化温度是影响生物炭制备的优先考虑因素,秸秆生物炭的炭产率随热解温度的升高而减小,其pH值和灰分则相应增大;相较于小麦秸杆和油菜秸杆生物炭,水稻秸秆的炭产率、pH值和灰分含量最高.温度为550℃,保温时间在60 min时,秸秆生物炭的官能团吸收振动峰趋于平缓,表面出现蜂窝状孔隙结构,表明其孔隙丰富,结构稳定.

Abstract

The physicochemical properties,functional group structure and morphology of the biochar derived from crop straw(such as wheat,rice,rape straw)biomass were determined and analyzd using sealed oxygen limiting treatment to prepare the straw biochar based on orthogonal experiment method.The results showed that the temperature of carbonization was the most important factor effect on yield,pH value and ash content of straw biochar.And the carbon yield decreased with temperature,while pH value and ash content increased correspondingly,where carbon yield,pH value and ash content of rice straw was the best.Particularly,the biochar's,obtained at 550℃for 60 min,were rich in honeycomb pore structure and absorption vibration peak of the functional groups tended to be flat,which indicated the pore structure was abundant and stable.

关键词

秸秆/生物炭/理化特性/热解温度/炭化时间

Key words

straw/biochar/physicochemical properties/pyrolysis temperature/residence time

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基金项目

安徽省教育厅项目(gxyq20037)

滁州市科技局项目(2022ZN014)

安徽省教育厅自然科学研究重大项目(2022AH040238)

安徽省粮食机械乡村振兴协同技术服务中心项目(GXXT-2022-077)

出版年

2024
太阳能学报
中国可再生能源学会

太阳能学报

CSTPCDCSCD北大核心
影响因子:0.392
ISSN:0254-0096
参考文献量30
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