太阳能学报2024,Vol.45Issue(3) :277-281.DOI:10.19912/j.0254-0096.tynxb.2022-1744

合成气/CO2火焰传播过程中辐射再吸收的影响

EFFECTS OF RADIATION REABSORPTION DURING FLAME PROPAGATION OF SYNGAS/CO2 MIXTURES

安秀丽 刘浩 何育臻 郑树 陆强
太阳能学报2024,Vol.45Issue(3) :277-281.DOI:10.19912/j.0254-0096.tynxb.2022-1744

合成气/CO2火焰传播过程中辐射再吸收的影响

EFFECTS OF RADIATION REABSORPTION DURING FLAME PROPAGATION OF SYNGAS/CO2 MIXTURES

安秀丽 1刘浩 1何育臻 1郑树 1陆强1
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作者信息

  • 1. 华北电力大学新能源发电国家工程研究中心,北京 102206
  • 折叠

摘要

针对生物质制取合成气燃料制备和应用过程中CO2掺混的影响,对合成气/空气/CO2预混火焰中开展数值模拟,通过不同的辐射模型研究辐射再吸收对火焰传播速度的影响.结果表明,辐射再吸收提高了火焰传播速度,最大提升幅度可达11.15%.随当量比增加,辐射再吸收对火焰传播速度的提升幅度从11.15%减小至3.12%,受预热导致的化学效应控制.H自由基在贫燃工况占据主导地位,辐射再吸收通过反应H+O2==O+OH影响火焰传播速度;而富燃工况下,与OH自由基相关的反应H+OH+M==H2O+M是辐射再吸收影响火焰传播速度的主导反应.

Abstract

Aiming at the effect of CO2 mixing in the preparation and application of syngas fuel from biomass,numerical simulations are conducted in syngas/air/CO2 flame,the effect of radiation reabsorption on laminar flame speed is studied by different radiation models.Results show that the radiation reabsorption increase the flame speed of syngas/air/CO2 mixtures,the relative increment is up to 11.15%.With the increase of equivalence ratio,the increase of flame speed induced by radiation reabsorption effect decrease from 11.15%to 3.12%,which is controlled by the preheat-induced chemical effect.H radicals play the dominant role in the fuel-lean conditions,and the radiation reabsorption effect affects the flame speed through the reaction H+O2==O+OH,while at the fuel-rich conditions,the reaction H+OH+M==H2O+M related to OH radicals is the dominant reaction.

关键词

合成气/H2/CO/辐射/二氧化碳/火焰传播速度

Key words

syngas/H2/CO/radiation/carbon dioxide/flame speed

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基金项目

国家自然科学基金(52276185)

国家自然科学基金(52276189)

中央高校基本科研业务费专项(2020JG005)

中央高校基本科研业务费专项(2020DF01)

出版年

2024
太阳能学报
中国可再生能源学会

太阳能学报

CSTPCDCSCD北大核心
影响因子:0.392
ISSN:0254-0096
参考文献量15
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