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合成气/CO2火焰传播过程中辐射再吸收的影响

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针对生物质制取合成气燃料制备和应用过程中CO2掺混的影响,对合成气/空气/CO2预混火焰中开展数值模拟,通过不同的辐射模型研究辐射再吸收对火焰传播速度的影响.结果表明,辐射再吸收提高了火焰传播速度,最大提升幅度可达11.15%.随当量比增加,辐射再吸收对火焰传播速度的提升幅度从11.15%减小至3.12%,受预热导致的化学效应控制.H自由基在贫燃工况占据主导地位,辐射再吸收通过反应H+O2==O+OH影响火焰传播速度;而富燃工况下,与OH自由基相关的反应H+OH+M==H2O+M是辐射再吸收影响火焰传播速度的主导反应.
EFFECTS OF RADIATION REABSORPTION DURING FLAME PROPAGATION OF SYNGAS/CO2 MIXTURES
Aiming at the effect of CO2 mixing in the preparation and application of syngas fuel from biomass,numerical simulations are conducted in syngas/air/CO2 flame,the effect of radiation reabsorption on laminar flame speed is studied by different radiation models.Results show that the radiation reabsorption increase the flame speed of syngas/air/CO2 mixtures,the relative increment is up to 11.15%.With the increase of equivalence ratio,the increase of flame speed induced by radiation reabsorption effect decrease from 11.15%to 3.12%,which is controlled by the preheat-induced chemical effect.H radicals play the dominant role in the fuel-lean conditions,and the radiation reabsorption effect affects the flame speed through the reaction H+O2==O+OH,while at the fuel-rich conditions,the reaction H+OH+M==H2O+M related to OH radicals is the dominant reaction.

syngasH2/COradiationcarbon dioxideflame speed

安秀丽、刘浩、何育臻、郑树、陆强

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华北电力大学新能源发电国家工程研究中心,北京 102206

合成气 H2/CO 辐射 二氧化碳 火焰传播速度

国家自然科学基金国家自然科学基金中央高校基本科研业务费专项中央高校基本科研业务费专项

52276185522761892020JG0052020DF01

2024

太阳能学报
中国可再生能源学会

太阳能学报

CSTPCD北大核心
影响因子:0.392
ISSN:0254-0096
年,卷(期):2024.45(3)
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