首页|基于蛾眼仿生结构的钙钛矿太阳电池表界面光学调控

基于蛾眼仿生结构的钙钛矿太阳电池表界面光学调控

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采用时域有限差分法(FDTD)和严格耦合波分析(RCWA),系统研究蛾眼仿生结构对钙钛矿太阳电池表面和界面的光学调控特性,同时通过等效介质理论(EMT)分析其中的增强机制.结果表明,蛾眼结构的引入可有效打破材料之间的界面限制,使折射率从突变转向梯度渐变,光波可几乎不受阻碍的穿过两种材料的交界面.经过优化调控,表面和界面的光学损失分别从3.52%和3.30%降到0.08%和0.06%,钙钛矿太阳电池的光电响应性能明显增强,转换效率相比平面电池提升14.93%.
OPTICAL MODULATION OF SURFACE/INTERFACE OF PEROVSKITE SOLAR CELLS BASED ON MOTH EYE BIO-INSPIRED STRUCTURE
The optical control characteristics of biomimetic moth-eye structures on the surface and interface of perovskite solar cells(PSCs)were systematically investigated using the Finite Difference Time Domain(FDTD)method and Rigorous Coupled Wave Analysis(RCWA),with the enhancement mechanisms analyzed through Equivalent Medium Theory(EMT).The results demonstrate that the introduction of moth-eye structures effectively breaks the interface limitations between materials,resulting in the refractive index to shift from adrupt change to gradient change.As a result,optical waves can pass through the interface between the two materials almost unhindered.With optimized regulation,the optical losses of the surface and interface decrease from the original 3.52%and 3.30%to 0.08%and 0.06%,respectively.Consequently,the photoelectric response performance of the cells is significantly enhanced,with an increase in energy conversion efficiency by 14.93%compared to planar cells.

perovskite solar cellsantireflection coatingsenergy conversion efficiencyfinite difference time domain method

沈向前、韩非、蒋斯涵、江舟、周华

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新疆大学物理科学与技术学院,新疆固态物理与器件重点实验室,乌鲁木齐 830046

山东大学物理学院,济南 250100

钙钛矿太阳电池 抗反射结构 能量转换效率 时域有限差分方法

新疆维吾尔自治区自然科学基金新疆自治区天山创新团队项目

2022D01C202023D14001

2024

太阳能学报
中国可再生能源学会

太阳能学报

CSTPCD北大核心
影响因子:0.392
ISSN:0254-0096
年,卷(期):2024.45(4)
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