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天然橡胶内生糖结构及热变性研究

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采用中红外(MIR)光谱法研究了天然橡胶内生糖结构;采用变温MIR光谱法研究了内生糖结构变温去卷积MIR光谱;采用二维MIR光谱法研究了内生糖结构热变性.结果表明,在293 K-393 K范围内,随着测试温度的升高,内生糖晶体结构对应的吸收波数发生明显变化;内生糖结构对热敏感程度及官能团变化快慢顺序都有较大差异;在热扰动因素下,内生糖晶体结构的改变是整个内生糖结构改变的一个关键步骤.
Study on Endogenous Sugar Structure and Thermal Denaturation of Natural Rubber
The endogenous sugar structure of natural rubber was studied by mid-infrared(MIR)spectroscopy.The variable temperature deconvolution MIR spectra of endogenous sugar structures was studied by variable temperature MIR spectroscopy.The structural thermal denaturation of endog-enous sugars was studied by 2 D MIR spectroscopy.The results showed that in the range of 293 K~393 K,the absorption wave number corresponding to the endogenous sugar crystal structure changed significantly with the increase of the test temperature.There were significant differences in the thermal sensitivity of endogenous sugar structure and the speed order of functional group change.Under ther-mal disturbance factors,the change of endogenous sugar crystal structure was a key step in the entire endogenous sugar structure change.

natural rubberendogenous sugarsmid-infrared MIR spectroscopyvariable tempera-ture MIR spectroscopy2 D MIR spectroscopythermal denaturation

刘荣、吉一帆、柴嘉欣、周悦茉、韩一诺、于宏伟

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石家庄学院化工学院,石家庄 050035

河北省麻醉药技术创新中心,石家庄 050035

天然橡胶 内生糖 中红外MIR光谱 变温MIR光谱 二维MIR光谱 热变性

石家庄麻醉药技术创新中心项目河北省生物制药国际联合中心项目

石科[2019]34号冀科外函[2022]3号

2024

特种橡胶制品
西北橡胶塑料研究设计院

特种橡胶制品

影响因子:0.28
ISSN:1005-4030
年,卷(期):2024.45(2)
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