首页|EVA/CR TPV的压缩应力松弛及其可逆回复行为

EVA/CR TPV的压缩应力松弛及其可逆回复行为

扫码查看
采用动态硫化法制备了基于乙烯-醋酸乙烯酯共聚物(EVA)/氯丁橡胶(CR)的热塑性硫化胶(TPV),并对其力学行为、微观结构、压缩应力松弛、可逆回复行为以及EVA/CR质量比对可逆回复不同阶段应力松弛行为的影响进行了研究.结果表明:EVA/CR TPV的压缩应力松弛行为主要受EVA相影响,CR分散相对压缩应力松弛行为的影响较小;提高热处理温度或延长热处理时间,均可显著提高TPV压缩应力松弛可逆回复程度,且当温度在EVA熔点附近时,TPV应力松弛的可逆回复程度接近100%.
Compression Stress Relaxation and Its Reversibility of Ethylene-vinyl Acetate Copolymer/Chloroprene Rubber Thermoplastic Vulcanizate
Thermoplastic vulcanizate(TPV)based on ethylene-vinyl acetate copolymer(EVA)/chloroprene rubber(CR)blend was prepared by dynamic vulcanization.The mechanical properties,microstructure,the stress relaxation behavior under compression mode and its reversibility were in-vestigated systematically.The model construction of reversibility of TPV were carried out by data fit-ting and the influences of blending ratio on the relaxation behavior were discussed.The results showed that the stress relaxation of the EVA/CR TPV was mainly determined by the EVA phase,while the dispersed phase of CR only had a minor influence on the compressive stress relaxation behavior.In-creasing the heat-treatment temperature or prolonging the heat treatment duration could also enhance the degree of reversible recovery behavior of the compressive stress relaxation,and the reversible-re-covery degree of EVA/CR TPV was close to 100%when heat-treatment temperature approached EVA melting point.

ethylene-vinyl acetate copolymerchloroprene rubberthermoplastic vulcanizatecompression stress relaxationreversibility

褚建强、陆逊、朱大志、王兆波

展开 >

青岛科技大学材料科学与工程学院,山东青岛 266042

青岛海信信息产业园,山东青岛 266510

乙烯-醋酸乙烯酯共聚物 氯丁橡胶 热塑性硫化胶 压缩应力松弛 可逆回复

山东省自然科学基金

ZR2021ME028

2024

特种橡胶制品
西北橡胶塑料研究设计院

特种橡胶制品

影响因子:0.28
ISSN:1005-4030
年,卷(期):2024.45(5)