特种橡胶制品2024,Vol.45Issue(5) :1-5.

EVA/CR TPV的压缩应力松弛及其可逆回复行为

Compression Stress Relaxation and Its Reversibility of Ethylene-vinyl Acetate Copolymer/Chloroprene Rubber Thermoplastic Vulcanizate

褚建强 陆逊 朱大志 王兆波
特种橡胶制品2024,Vol.45Issue(5) :1-5.

EVA/CR TPV的压缩应力松弛及其可逆回复行为

Compression Stress Relaxation and Its Reversibility of Ethylene-vinyl Acetate Copolymer/Chloroprene Rubber Thermoplastic Vulcanizate

褚建强 1陆逊 2朱大志 1王兆波1
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作者信息

  • 1. 青岛科技大学材料科学与工程学院,山东青岛 266042
  • 2. 青岛海信信息产业园,山东青岛 266510
  • 折叠

摘要

采用动态硫化法制备了基于乙烯-醋酸乙烯酯共聚物(EVA)/氯丁橡胶(CR)的热塑性硫化胶(TPV),并对其力学行为、微观结构、压缩应力松弛、可逆回复行为以及EVA/CR质量比对可逆回复不同阶段应力松弛行为的影响进行了研究.结果表明:EVA/CR TPV的压缩应力松弛行为主要受EVA相影响,CR分散相对压缩应力松弛行为的影响较小;提高热处理温度或延长热处理时间,均可显著提高TPV压缩应力松弛可逆回复程度,且当温度在EVA熔点附近时,TPV应力松弛的可逆回复程度接近100%.

Abstract

Thermoplastic vulcanizate(TPV)based on ethylene-vinyl acetate copolymer(EVA)/chloroprene rubber(CR)blend was prepared by dynamic vulcanization.The mechanical properties,microstructure,the stress relaxation behavior under compression mode and its reversibility were in-vestigated systematically.The model construction of reversibility of TPV were carried out by data fit-ting and the influences of blending ratio on the relaxation behavior were discussed.The results showed that the stress relaxation of the EVA/CR TPV was mainly determined by the EVA phase,while the dispersed phase of CR only had a minor influence on the compressive stress relaxation behavior.In-creasing the heat-treatment temperature or prolonging the heat treatment duration could also enhance the degree of reversible recovery behavior of the compressive stress relaxation,and the reversible-re-covery degree of EVA/CR TPV was close to 100%when heat-treatment temperature approached EVA melting point.

关键词

乙烯-醋酸乙烯酯共聚物/氯丁橡胶/热塑性硫化胶/压缩应力松弛/可逆回复

Key words

ethylene-vinyl acetate copolymer/chloroprene rubber/thermoplastic vulcanizate/compression stress relaxation/reversibility

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基金项目

山东省自然科学基金(ZR2021ME028)

出版年

2024
特种橡胶制品
西北橡胶塑料研究设计院

特种橡胶制品

影响因子:0.28
ISSN:1005-4030
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