首页|Ce2O3含量对WC基硬质合金微观组织和性能影响

Ce2O3含量对WC基硬质合金微观组织和性能影响

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以不同的WC粉末(铸造WC、球形WC和细粒WC)和Ni粉作骨架成分,CuNi合金为黏接金属,采用无压熔渗法在1 200℃下保温1 h制备WC基硬质合金,研究添加不同含量的Ce2O3(0,0.2%,0.4%,0.6%,0.8%和1.0%)对WC基硬质合金组织和力学性能的影响.结果表明,WC在试验温度下发生了不同程度的分解或溶解,同时熔渗过程中有新相生成,如C、W2C和Ni2W4C.微观组织中板条状形貌的WC有利于硬度和抗弯强度的提高,适量Ni2W4C相有利于冲击韧度的提高.当Ce2O3 含量为 0.6%时,合金硬度(HRA)和抗弯强度达到了最高值,分别为93.5和1 844.7 MPa;当Ce2O3含量为1.0%时,冲击韧度最高,为6.45 J/cm2.
Effects of Ce2O3 Content on Microstructure and Properties of WC-based Cemented Carbide
Taking different types of WC powders(cast WC,spherical WC,and fine-grained WC)and nickel powder as skeleton,and CuNi alloy as bonding metal,WC-based cemented carbide was fabricated by non-pressure fusion method at 1 200℃for 1 h.Effects of different amounts of Ce2O3(0%,0.2%,0.4%,0.6%,0.8%,and 1.0%)on microstructure and mechanical properties of WC-based cemented carbide were investigated.The results indicate that WC is decomposed or dissolved to varying degrees at experimental temperatures.Simultaneously,new phases,such as C,W2C,and Ni2W4C,are generated during fusion process.The plate-shaped WC in the microstructure is condu-cive to enhancing hardness and bending strength,while the presence of Ni2W4C is helpful to enhance impact toughness.Hardness and bending strength reach the maximum values of 93.5 HRA and 1 844.7 MPa,respectively,when Ce2O3 content is 0.6%,and the highest impact toughness of 6.45 J/cm2 can be obtained at a Ce2O3 content of 1.0%.

WCCemented CarbideCe2O3MicrostructureMechanical Property

张旭东、李秀兰、周新军、蒋啸、陈尧

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四川轻化工大学机械工程学院,宜宾 644005

WC 硬质合金 Ce2O3 微观组织 力学性能

四川省科技计划资助项目四川轻化工大学研究生创新基金资助项目自贡市科技局重点科技计划资助项目四川轻化工大学人才引进资助项目

2022YFG0289Y20230802018YYJC082018RCL12

2024

特种铸造及有色合金
中国机械工程学会铸造分会

特种铸造及有色合金

CSTPCD北大核心
影响因子:0.481
ISSN:1001-2249
年,卷(期):2024.44(4)
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