首页|不同工艺处理下AZ91D镁合金耐腐蚀性能研究

不同工艺处理下AZ91D镁合金耐腐蚀性能研究

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通过光学显微镜、电镜、XRD对固溶态、挤压态、时效处理挤压态AZ91D合金进行显微组织分析观察;对铸态、固溶态、挤压态AZ91D镁合金进行动电位极化、盐雾腐蚀试验、浸泡腐蚀失重试验.结果表明,挤压态AZ91D镁合金耐腐蚀性能优于固溶态的,时效处理后的挤压态AZ91D镁合金耐腐蚀性能好于挤压态的.固溶处理使β-Mg17Al12相不断溶解于α基体中形成过饱和固溶体,固溶态AZ91D镁合金在热挤压过程中不断从过饱和固溶体α基体中析出大量沿晶界分布的β相.Al元素可提高镁合金的腐蚀电位,降低镁合金腐蚀倾向性,从而延缓了腐蚀速度,使挤压态AZ91D镁合金的耐腐蚀性能提升.时效过程消除了在热挤压过程中材料内部出现的残余应力,使β-Mg17Al12相沿晶界分布更为均匀,进一步提升了AZ91D镁合金的耐腐蚀性能.
Corrosion Resistance of AZ91D Magnesium Alloy under Different Treatment Processes
The microstructure of solid solution,as-extruded AZ91D and aged-extruded AZ91D magnesium alloy was analyzed by optical microscopy,electron microscopy and XRD.AZ91D magnesium alloy in the as-cast,solid solution,and extruded states was analyzed through potential polarization,salt spray corrosion,and immersion corrosion weight loss experiments.The results indicate that the corrosion resistance of extruded AZ91D magnesium alloy is superior to that of solid solution ones,and that of extruded AZ91D magnesium alloy after aging treatment is better than that of extruded ones.After solid solution treatment,β-Mg17Al12 phase is continuously dissolved into α matrix to form the supersaturated solid solution,and a large amount of β phases are precipitated from supersaturated solid solution α phase in the solid solution AZ91D magnesium alloy during the hot extrusion process,which are distributed along grain bound-aries.Corrosion resistance of as-extruded AZ91D is improved as a result of Al increasing the corrosion potential of magnesium alloys,reducing corrosion tendency to delay the corrosion rate.The aging process can eliminate residual stresses that occurs in the material during hot extrusion,resulting in the more uniform distribution of β-Mg17Al12 phase along grain boundaries,further improving the corrosion resistance of AZ91D magnesium alloy.

Magnesium AlloyHeat TreatmentExtrusionMicrostructureCorrosion Resistance

付广艳、杨龙飞、薛丰

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沈阳化工大学机械与动力工程学院,沈阳 110142

镁合金 热处理 挤压 显微组织 耐腐蚀性

国家自然科学基金

52201131

2024

特种铸造及有色合金
中国机械工程学会铸造分会

特种铸造及有色合金

CSTPCD北大核心
影响因子:0.481
ISSN:1001-2249
年,卷(期):2024.44(5)
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