首页|Zr对亚共晶Al-Si-Cu-Ni-Mg多元合金组织性能的影响

Zr对亚共晶Al-Si-Cu-Ni-Mg多元合金组织性能的影响

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通过直读式光谱仪、差式扫描量热分析仪(DSC)、场发射扫描电镜(SEM)、万能试验机和电化学工作站等研究了 Zr对亚共晶Al-9.5Si-5Cu-2.5Ni-0.5Mg多元合金凝固过程、微观组织、力学性能及耐蚀性能的影响.结果表明,Zr会在Al3CuNi相中微量掺杂,形成Al3(CuSiZr)Ni相,Zr的掺杂对物相结构无影响,但使其形貌由连续的网状演变为离散的板片状,导致耐热相间的搭接连续性和联通率显著降低,这是该多元合金的室温和高温抗拉强度随Zr含量增加(Zr≤0.2%)呈下降趋势的主要原因.此外,Zr会降低合金的自腐蚀电位,同时因Al3CuNi相形貌演变导致腐蚀过程中生成的氧化膜更不完整,使合金耐蚀性变差,且Zr添加量(Zr≤0.2%)越高耐蚀性越差.
Effects of Zr on Microstructure and Properties of Hypoeutectic Al-Si-Cu-Ni-Mg Multi-element Alloy
Effects of Zr on solidification process,microstructure,mechanical properties and corrosion resistance of hypoeutectic Al-9.5Si-5Cu-2.5Ni-0.5Mg multi-alloy were investigated by direct-reading spectrometer,differential scanning calorimetry(DSC),field emission scanning electron microscope(SEM),universal testing machine and elec-trochemical workstation.The results indicate that Zr is trace doped in Al3CuNi phase,leading to Al3(CuSiZr)Ni phase.Zr doping hardly affects the phase structure,resulting in the morphology transformation from continuous network to discrete flaky,obviously reducing the overlap continuity and connectivity between the heat-resistant phases,which is the main reason that the room temperature and high temperature tensile strength are decreased with increasing Zr con-tent(Zr≤0.2%).In addition,Zr can reduce the corrosion potential of alloy,and the evolution of Al3CuNi phase mor-phology leads to incomplete oxide films during the corrosion process,which deteriorates the corrosion resistance of the alloy.Moreover,the corrosion resistance is worse with Zr content increasing.

Al-Si AlloyMicrostructureMechanical PropertiesCorrosion ResistancePiston

孙缘、韩梦霞、侯星驰、徐海龙、贾志洁、刘相法

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山东大学材料科学与工程学院,材料液固结构演变与加工教育部重点实验室,济南 250061

山东力信铝业科技有限公司,滨州 256600

山东省高端铝共同体管理运营有限公司,滨州 256606

Al-Si合金 微观组织 力学性能 耐蚀性能 活塞

2024

特种铸造及有色合金
中国机械工程学会铸造分会

特种铸造及有色合金

CSTPCD北大核心
影响因子:0.481
ISSN:1001-2249
年,卷(期):2024.44(12)