首页|Preparation, Characterization, and Performance of Lignin-based Microencapsulated Red Phosphorus Flame Retardant for ABS

Preparation, Characterization, and Performance of Lignin-based Microencapsulated Red Phosphorus Flame Retardant for ABS

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The inherent difficulty in preservation and processing of conventional red phosphorus flame retardant severely limits its growing applications in polymer materials, thus, there is an urgent need to exploit effective technology to modify red phosphorus. Functionalized lignin-based compounds can provide a great potential in improving the preservation and processing of red phosphorus. Here, we prepared melamine modified lignin/aluminum phosphate coated red phosphorus (LMAP@RP) and used it as the flame retardant of acrylonitrile-butadiene-styrene (ABS) resin. With 25wt% loading LMAP@RP, the ABS samples show excellent flame inhibiting capacity and reached UL-94 V-0 rating. Cone calorimetry test results show that the peak heat release rate, total heat release and total smoke release of ABS/25LMAP@RP are reduced strikingly by 64.6%, 49.3%, and 30.1%, respectively. The char residue is 15.36wt% and the char layer is continuous and dense. The outstanding flame retardant and smoke-suppressant performances of LMAP@RP show its application prospect for ABS.

ligninred phosphorusABSflame retardant

XIONG Lei、HUANG Shaohuai、ZHONG Rouchao、TANG Weizhong、LIU Chao、JIN Yanqiao

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College of Materials Science and Engineering,Fuzhou University,Fuzhou 350108,China

China National R&D Center for Tungsten Technology,Xiamen Tungsten Co.,Ltd,Xiamen 361009,China

国家自然科学基金福建省自然科学基金

515030412018J01752

2022

武汉理工大学学报(材料科学版)(英文版)
武汉理工大学

武汉理工大学学报(材料科学版)(英文版)

CSTPCDCSCDSCI
影响因子:0.253
ISSN:1000-2413
年,卷(期):2022.37(2)
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