无机材料学报2024,Vol.39Issue(12) :1325-1330.DOI:10.15541/jim20240156

喷墨打印制备AgCuTe热电薄膜

Inkjet Printing Preparation of AgCuTe Thermoelectric Thin Films

张波涛 孙婷婷 王连军 江莞
无机材料学报2024,Vol.39Issue(12) :1325-1330.DOI:10.15541/jim20240156

喷墨打印制备AgCuTe热电薄膜

Inkjet Printing Preparation of AgCuTe Thermoelectric Thin Films

张波涛 1孙婷婷 2王连军 1江莞3
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作者信息

  • 1. 东华大学材料科学与工程学院,纤维改性国家重点实验室,上海 201620
  • 2. 东华大学生物与医学工程学院,上海 201620
  • 3. 东华大学材料科学与工程学院,纤维改性国家重点实验室,上海 201620;东华大学功能材料研究中心,上海 201620
  • 折叠

摘要

柔性热电器件可以利用人体与环境之间的微小温差发电,在可穿戴设备的持续供电领域展现出巨大的潜力,但较低的热电性能限制了柔性热电器件的广泛应用.本研究报道了一种利用喷墨打印制备高性能柔性热电薄膜的方法.将利用化学转移法制备的AgCuTe纳米线分散在乙醇溶剂中,得到的墨水无明显沉降,能稳定持续喷射,将其喷印在聚酰亚胺衬底上得到p型热电薄膜.随后利用放电等离子烧结炉进行热处理,得到了致密的热电薄膜,并研究了烧结温度对热电性能的影响.结果表明,在10 MPa、400 ℃下烧结15 min后,室温下薄膜功率因子为432 μW·m-1·K-2,比现有文献报道的喷墨打印p型Bi2Te3薄膜的室温功率因子(153 μW·m-1·K-2)提高了 182%.本研究进一步拓宽了喷墨打印在柔性热电器件领域的应用,同时也为制备新一代高性能柔性热电器件提供了更多可能.

Abstract

Flexible thermoelectric devices,capable of generating electricity from the slight temperature difference between the human body and the environment,demonstrate significant potential for continuous power supply in wearable devices.However,the poor thermoelectric performance still limits their widespread application.This study reports a method for fabricating high-performance flexible thermoelectric thin films using inkjet printing.AgCuTe nanowires prepared by a chemical transfer method were dispersed in ethanol to form the ink with no significant sedimentation,which could be stably and continuously sprayed to print p-type thermoelectric films on polyimide substrates.Dense thermoelectric films were then obtained through thermal treatment by a spark plasma sintering furnace,and the effect of sintering temperature on thermoelectric properties was studied.The results showed that the film sintered at a pressure of 10 MPa and a temperature of 400 ℃ for 15 min possessed a room temperature power factor of 432 μW·m-1·K-2,which is 182%higher than that of inkjet-printed p-type Bi2Te3 films(a room temperature power factor of 153 μW·m-1·K-2)reported in literature.This advancement further expands the application of inkjet printing in the field of flexible thermoelectrics and provides more possibilities for the fabrication of a new generation of high-performance flexible thermoelectric devices.

关键词

喷墨打印/柔性热电薄膜/AgCuTe/墨水

Key words

inkjet printing/flexible thermoelectric thin film/AgCuTe/ink

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出版年

2024
无机材料学报
中国科学院上海硅酸盐研究所

无机材料学报

CSTPCD北大核心
影响因子:0.768
ISSN:1000-324X
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