The removal of hexanal was studied using a combination of non-thermal plasma and catalyst. The results showed that there was a synergistic function between the plasma and natural mordenite (NMOR) with a hexanal removal efficiency of 93.9% at 80℃. and 2.8 W discharge power. The removal efficiency can be further improved to 96.5% when natural mordenite was treated using 6 mol·L-1 HC1 for 6 h. Natural mordenite was stable and the removal efficiency did not declined with a continuous use of 55 h.