Reactions of(Et4N)(Tp*WS3)(A)(Tp*=hydridotris(3,5-dimethylpyrazol-1-yl)borate)and Cu(Ⅰ)salts[Cu(MeCN)4]PF6 with di(pyridin-4-yl)sulfane(L1)or bis(4-(pyridin-4-yl)phenyl)methanone(L2)gave rise to two W/Cu/S cluster-based supramolecular compounds with the formula of[Tp*WS3Cu2(L1)]2(PF6)2·2MeCN·2CHCl3(1·2MeCN· 2CHCl3)and[Tp*WS3Cu2(L2)(MeCN)]2(PF6)2·4MeCN(2·4MeCN),respectively.Both cluster-based supramolecular compounds were structurally characterized by single-crystal X-ray diffraction,1H NMR,MS,IR,UV-Vis,and elemental analysis.Single crystal X-ray diffraction demonstrates that both compounds are cationic cluster-based supramolecule frames with similar butterfly-like cores.1H NMR and high-resolution electrospray ionization mass spectrometry(HRESI-MS)demonstrated their stability in DMF solution.In addition,the Z-scan measurement reveals the third-order nonlinear optical responses of 1·2MeCN·2CHCl3 and 2·4MeCN were enhanced compared to that of their precursor A.CCDC:2257638,1·2MeCN·2CHCl3;2257639,2·4MeCN.
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