无机化学学报2024,Vol.40Issue(3) :581-590.DOI:10.11862/CJIC.20230253

泡沫镍负载NiMoO4/NiMoS4复合材料的制备及其电化学性能

Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites

郑佳红 申嘉钧 白昕
无机化学学报2024,Vol.40Issue(3) :581-590.DOI:10.11862/CJIC.20230253

泡沫镍负载NiMoO4/NiMoS4复合材料的制备及其电化学性能

Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites

郑佳红 1申嘉钧 1白昕1
扫码查看

作者信息

  • 1. 长安大学材料科学与工程学院,西安 710061
  • 折叠

摘要

以泡沫镍作为基底,采用水热法原位生长出具有片状结构的NiMoO4活性材料,然后通过水热硫化制备出 NiMoO4/NiMoS4复合材料,研究了水热时间和硫脲添加量对样品形貌和电化学性能的影响.电化学结果表明,NiMoO4/NiMoS4电极在电流密度为1 A·g-1时,比电容为1 560.7 F·g-1,在电流密度为40 A·g-1时循环2 000次后,比电容仍为初始比电容的76.7%.将NiMoO4/NiMoS4电极材料与活性炭(AC)分别作为正、负极组装的非对称超级电容器(ASC)在400 W·kg-1的功率密度下可提供29.0 Wh· kg-1的能量密度.

Abstract

Using nickel foam as a substrate,NiMoO4 active materials with sheet-like structures were produced in situ,and later NiMoO4/NiMoS4 composites were prepared by vulcanization.On the morphology and electrochemical char-acteristics of the materials,the impacts of hydrothermal time and thiourea addition were examined.Electrochemical experiments revealed that the NiMoO4/NiMoS4 electrode could release a specific capacitance of 1 560.7 F·g-1 at a current density of 1 A·g-1,and the capacity remained at 76.7%of the initial specific capacitance after 2 000 cycles at a current density of 40 A·g-1.The asymmetric supercapacitors(ASC)device assembled with NiMoO4/NiMoS4 elec-trode material and activated carbon(AC)as positive and negative electrodes respectively can provide 29.0 Wh·kg-1 energy density at a power density of 400 W·kg-1.

关键词

硫化物/超级电容器/电化学性能

Key words

sulfide/supercapacitor/electrochemical property

引用本文复制引用

基金项目

陕西省重点研发项目(2024GX-YBXM-384)

长安大学中央高校基本科研业务费专项(300102311405)

长安大学中央高校基本科研业务费专项(300102312405)

长安大学中央高校基本科研业务费专项(300102312406)

大学生创新创业训练计划项目(S202310710271)

大学生创新创业训练计划项目(X202310710415)

出版年

2024
无机化学学报
中国化学会

无机化学学报

CSTPCDCSCD北大核心
影响因子:0.665
ISSN:1001-4861
参考文献量30
段落导航相关论文