首页|泡沫镍负载NiMoO4/NiMoS4复合材料的制备及其电化学性能

泡沫镍负载NiMoO4/NiMoS4复合材料的制备及其电化学性能

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以泡沫镍作为基底,采用水热法原位生长出具有片状结构的NiMoO4活性材料,然后通过水热硫化制备出 NiMoO4/NiMoS4复合材料,研究了水热时间和硫脲添加量对样品形貌和电化学性能的影响.电化学结果表明,NiMoO4/NiMoS4电极在电流密度为1 A·g-1时,比电容为1 560.7 F·g-1,在电流密度为40 A·g-1时循环2 000次后,比电容仍为初始比电容的76.7%.将NiMoO4/NiMoS4电极材料与活性炭(AC)分别作为正、负极组装的非对称超级电容器(ASC)在400 W·kg-1的功率密度下可提供29.0 Wh· kg-1的能量密度.
Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites
Using nickel foam as a substrate,NiMoO4 active materials with sheet-like structures were produced in situ,and later NiMoO4/NiMoS4 composites were prepared by vulcanization.On the morphology and electrochemical char-acteristics of the materials,the impacts of hydrothermal time and thiourea addition were examined.Electrochemical experiments revealed that the NiMoO4/NiMoS4 electrode could release a specific capacitance of 1 560.7 F·g-1 at a current density of 1 A·g-1,and the capacity remained at 76.7%of the initial specific capacitance after 2 000 cycles at a current density of 40 A·g-1.The asymmetric supercapacitors(ASC)device assembled with NiMoO4/NiMoS4 elec-trode material and activated carbon(AC)as positive and negative electrodes respectively can provide 29.0 Wh·kg-1 energy density at a power density of 400 W·kg-1.

sulfidesupercapacitorelectrochemical property

郑佳红、申嘉钧、白昕

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长安大学材料科学与工程学院,西安 710061

硫化物 超级电容器 电化学性能

陕西省重点研发项目长安大学中央高校基本科研业务费专项长安大学中央高校基本科研业务费专项长安大学中央高校基本科研业务费专项大学生创新创业训练计划项目大学生创新创业训练计划项目

2024GX-YBXM-384300102311405300102312405300102312406S202310710271X202310710415

2024

无机化学学报
中国化学会

无机化学学报

CSTPCD北大核心
影响因子:0.665
ISSN:1001-4861
年,卷(期):2024.40(3)
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