无机化学学报2024,Vol.40Issue(4) :686-692.DOI:10.11862/CJIC.20230388

Sm3+掺杂Ba0.85Ca0.15Ti0.90Zr0.10O3无铅多功能铁电陶瓷的储能和光致发光性能

Energy storage and photoluminescence properties of Sm3+-doped Ba0.85Ca0.15Ti0.90Zr0.10O3 lead-free multifunctional ferroelectric ceramics

郑明 张怡笑 杨健 关朋飞 李秀东
无机化学学报2024,Vol.40Issue(4) :686-692.DOI:10.11862/CJIC.20230388

Sm3+掺杂Ba0.85Ca0.15Ti0.90Zr0.10O3无铅多功能铁电陶瓷的储能和光致发光性能

Energy storage and photoluminescence properties of Sm3+-doped Ba0.85Ca0.15Ti0.90Zr0.10O3 lead-free multifunctional ferroelectric ceramics

郑明 1张怡笑 1杨健 1关朋飞 1李秀东1
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作者信息

  • 1. 中国矿业大学材料与物理学院,徐州 221116
  • 折叠

摘要

通过高温固相反应法制备了 Ba0.85Ca0.15Ti0.90Zr0.10O3∶xSm3+(BCTZ∶xSm3+,x=0.0%、0.2%、0.4%、0.6%、0.8%、1.0%,物质的量分数)陶瓷,系统研究了其微观形貌、铁电性能、储能性能和光致发光性能.研究表明,Sm3+掺入后,陶瓷平均晶粒大小明显下降,致密度显著提高.所有陶瓷均表现出典型的铁电性.BCTZ∶xSm3+陶瓷放电储能密度得到了极大的提高,BCTZ∶1.0%Sm3+陶瓷放电储能密度较纯BCTZ陶瓷可提高约49.0%.此外,在408 nm光的激发下,BCTZ∶xSm3+陶瓷在596 nm左右表现出强烈的橙红色发光,且发光强度相对可调性可达449%.

Abstract

Sm3+-doped Ba0.85Ca0.15Ti0.90Zr0.10O3(BCTZ∶xSm3+,x=0.0%,0.2%,0.4%,0.6%,0.8%,1.0%,mole fraction)ceramics were synthesized using the conventional solid state reaction method,and their microstructure,ferroelectric-ity,energy storage performance,and photoluminescence(PL)properties were systematically investigated.The results showed that the mean grain size of the ceramics decreased obviously and the density increased significantly after the addition of Sm3+.All ceramics exhibited typical ferroelectric properties.Moreover,with the further increase of doping amount,the remanent polarization(Pr)gradually decreased to 8.432 μC·cm-2(BCTZ∶1.0%Sm3+),and the ferroelectricity was suppressed.The energy storage density of BCTZ:1.0%Sm3+ceramic was improved by ca.49.0%compared with that of pure BCTZ ceramic.In addition,BCTZ∶xSm3+ceramics exhibit strong orange-red lumines-cence at about 596 nm under light excitation at 408 nm,and the PL intensity can be adjusted by 449%.

关键词

Ba0.85Ca0.15Ti0.90Zr0.10O3/Sm3+/铁电/储能/光致发光

Key words

Ba0.85Ca0.15Ti0.90Zr0.10O3/Sm3+/ferroelectricity/energy storage/photoluminescence

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基金项目

中央高校基本科研业务费专项资金(2022QN1087)

出版年

2024
无机化学学报
中国化学会

无机化学学报

CSTPCDCSCD北大核心
影响因子:0.665
ISSN:1001-4861
参考文献量23
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