无机化学学报2024,Vol.40Issue(9) :1708-1718.DOI:10.11862/CJIC.20240067

热分解制备CeO2-还原氧化石墨烯及其光催化性能

Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition

王卓 张俊山 杨绍艳 周玲艳 李叶迪 兰苑培
无机化学学报2024,Vol.40Issue(9) :1708-1718.DOI:10.11862/CJIC.20240067

热分解制备CeO2-还原氧化石墨烯及其光催化性能

Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition

王卓 1张俊山 2杨绍艳 2周玲艳 1李叶迪 1兰苑培2
扫码查看

作者信息

  • 1. 贵州大学材料与冶金学院,贵阳 550025
  • 2. 贵州大学材料与冶金学院,贵阳 550025;贵州省冶金工程与过程节能重点实验室,贵阳 550025
  • 折叠

摘要

通过一步水热法制备了CeCO3OH-rGO(还原氧化石墨烯),并在氩气(Ar)气氛下焙烧制备得到CeO2-rGO复合材料.采用X射线衍射、扫描电子显微镜、X射线光电子能谱以及紫外可见漫反射光谱(UV-Vis DRS)等研究了复合材料的物相组成、微观形貌、空位缺陷和光电化学特性等.对比研究了不同GO(氧化石墨烯)负载量和NH4HCO3添加量下所制备材料的光催化性能,发现GO负载量为10mg、NH4HCO3添加量为15 mmol的样品(CeO2-10rGO-15)具有最窄的禁带宽度(3.17 eV),对亚甲蓝(MB)的光催化降解率达80.66%.适宜的rGO负载量有利于促进CeO2空位缺陷的形成,也有利于光生载流子的分离,进而促进光催化性能.

Abstract

CeCO3OH-rGO(reduced graphene oxide)was prepared by a one-step hydrothermal method,and CeO2-rGO composites were prepared by roasting under argon(Ar)atmosphere.The phase composition,microstructure,vacancy defects,and photoelectrochemical properties of the composites were studied by X-ray diffraction,scanning electron microscopy,X-ray photoelectron spectroscopy,UV visible diffuse reflectance spectroscopy(UV-Vis DRS),etc.The photocatalytic performance of the composites with different GO(graphene oxide)and NH4HCO3 addition amounts respectively were comparatively studied.It was found that the CeO2-10rGO-15 with GO and NH4HCO3 addition amounts of 10 mg and 15 mmol respectively had the narrowest band-gap width(3.17 eV),and the photocat-alytic degradation ratio of methylene blue(MB)could reach 80.66%.It is beneficial to the formation vacancy defect of CeO2 and the separation of photogenic carriers for rGO loading suitably,thus promoting photocatalytic perfor-mance.

关键词

二氧化铈/氧化石墨烯/热分解/复合材料/光催化

Key words

CeO2/graphene oxide/thermal decomposition/composite/photocatalysis

引用本文复制引用

基金项目

国家自然科学基金(52164025)

&&(贵大培育[2019]30号)

&&(贵大SRT字2022012号)

出版年

2024
无机化学学报
中国化学会

无机化学学报

CSTPCDCSCD北大核心
影响因子:0.665
ISSN:1001-4861
参考文献量36
段落导航相关论文