无机化学学报2024,Vol.40Issue(10) :1861-1868.DOI:10.11862/CJIC.20240242

Eu3+掺杂CaLaGaO4红色荧光粉的制备及其荧光性能

Preparation and fluorescence properties of Eu3+-doped CaLaGaO4 red-emitting phosphors

赵炎 蒋小康 李忠辉 王佳旭 周恒为 郭海
无机化学学报2024,Vol.40Issue(10) :1861-1868.DOI:10.11862/CJIC.20240242

Eu3+掺杂CaLaGaO4红色荧光粉的制备及其荧光性能

Preparation and fluorescence properties of Eu3+-doped CaLaGaO4 red-emitting phosphors

赵炎 1蒋小康 1李忠辉 1王佳旭 1周恒为 1郭海2
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作者信息

  • 1. 伊犁师范大学物理科学与技术学院,凝聚态相变与微结构实验室,伊宁 835000
  • 2. 浙江师范大学物理系,金华 321004
  • 折叠

摘要

采用高温固相法制备不同浓度Eu3+掺杂CaLaGaO4系列红色荧光粉.研究结果显示,该系列荧光粉能够被392 nm的近紫外光有效激发,在609 nm处有强烈的红光发射,其光强主要依赖于Eu3+的5D0→7F2跃迁所发射的光,且在Eu3+浓度达到0.3时发光强度达到最大,其色坐标为(0.613,0.359),与标准红光坐标(0.670,0.330)较为接近,色纯度高达96.3%.由于热猝灭效应,当样品温度升高至498 K时,发光强度仍保持室温下的75%,激活能为0.151 3 eV.

Abstract

A series of Eu3+-doped CaLaGaO4 red-emitting phosphors with different concentrations were prepared via the high-temperature solid phase method.The results indicate that the obtained phosphors can be effectively pumped by a 392 nm near-ultraviolet light.The Eu3+-doped CaLaGaO4 phosphor displayed the characteristic transi-tions of Eu3+with the strongest emission at 609 nm,originating from 5D0→7F2 transition and the luminescence inten-sity reached its maximum when the concentration of Eu3+reached 0.3.In addition,the phosphor demonstrated a remarkable color purity value of 96.3%with CIE coordinates(0.613,0.359)lying closer to the ideal red color CIE coordinates(0.670,0.330).Furthermore,the photoluminescence emission intensity maintained 75%at 498 K com-pared to 298 K due to the thermal quenching effect,showcasing excellent thermal stability with an activation energy of 0.151 3 eV.

关键词

高温固相/CaLaGaO4/红色荧光粉/高热稳定性

Key words

high-temperature solid phase/CaLaGaO4/red-emitting phosphor/high thermal stability

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基金项目

伊犁师范大学新疆凝聚态相变与微结构实验室开放课题(XJDX0912Z2405)

伊犁师范大学研究生科研创新项目(YSD2024G004)

出版年

2024
无机化学学报
中国化学会

无机化学学报

CSTPCDCSCD北大核心
影响因子:0.665
ISSN:1001-4861
参考文献量45
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