无机化学学报2024,Vol.40Issue(10) :1911-1918.DOI:10.11862/CJIC.20240105

二维层状α-In2Se3(2H)铁电材料的各向异性光响应

Anisotropic photoresponse of two-dimensional layered α-In2Se3(2H)ferroelectric materials

吕宝华 李玉珍
无机化学学报2024,Vol.40Issue(10) :1911-1918.DOI:10.11862/CJIC.20240105

二维层状α-In2Se3(2H)铁电材料的各向异性光响应

Anisotropic photoresponse of two-dimensional layered α-In2Se3(2H)ferroelectric materials

吕宝华 1李玉珍2
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作者信息

  • 1. 运城学院应用化学系,运城 044000
  • 2. 运城学院工科实验实训中心,运城 044000
  • 折叠

摘要

采用机械剥离法制备了 2H相α-In2Se3[α-In2Se3(2H)]纳米片.通过X射线衍射(X-ray diffraction,XRD)、拉曼光谱、球差电镜和压电力显微镜对纳米片的结构和铁电性能进行详细表征,确定纳米片为具有特殊结构的α-In2Se3(2H)铁电材料.进一步在SiO2/Si基片上成功构造了基于α-In2Se3(2H)铁电的平面四端器件,详细研究其在各个方向的光响应.结果表明,具有本征结构的α-In2Se3(2H)在相互垂直方向均没有光响应.在器件两端分别施加电压后,α-In2Se3(2H)器件在相互垂直方向均出现了明显的光响应,尤其在接近于易极化轴方向施加电压后,α-In2Se3(2H)器件出现了各向异性光响应.

Abstract

The mechanical stripping method prepared the 2H-phase α-In2Se3(α-In2Se3(2H))nanosheets.The struc-ture and ferroelectric properties of the nanosheets were characterized by X-ray diffraction(XRD),Raman spectrosco-py,spherical aberration electron microscopy,and piezoelectric force microscopy.The nanosheets were identified asα-In2Se3(2H)ferroelectric materials with a special structure.Further,a planar four-terminal device based on α-In2Se3(2H)ferroelectricity was successfully constructed on the SiO2/Si substrate,and its photoresponse in all directions was investigated in detail.The results show that α-In2Se3(2H)with intrinsic structure has no photoresponse in both mutually perpendicular directions.After applying voltages at each end of the device,the α-In2Se3(2H)device shows obvious photoresponse in the mutually perpendicular directions.In particular,after utilizing a point voltage close to the direction of the easy polarization axis,the α-In2Se3(2H)device shows an anisotropic photoresponse.

关键词

二维层状α-In2Se3(2H)/机械剥离法/铁电性/各向异性光响应

Key words

two-dimensional layered α-In2Se3(2H)/mechanical stripping method/ferroelectricity/anisotropic photoresponse

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基金项目

国家自然科学基金(52002232)

山西省高校科技创新项目(2022L477)

运城学院博士科研启动项目(YQ-2023024)

先进永磁材料与技术省部共建协同创新中心2022年度规划课题(2022-06)

出版年

2024
无机化学学报
中国化学会

无机化学学报

CSTPCDCSCD北大核心
影响因子:0.665
ISSN:1001-4861
参考文献量29
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