首页|二维层状α-In2Se3(2H)铁电材料的各向异性光响应

二维层状α-In2Se3(2H)铁电材料的各向异性光响应

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采用机械剥离法制备了 2H相α-In2Se3[α-In2Se3(2H)]纳米片。通过X射线衍射(X-ray diffraction,XRD)、拉曼光谱、球差电镜和压电力显微镜对纳米片的结构和铁电性能进行详细表征,确定纳米片为具有特殊结构的α-In2Se3(2H)铁电材料。进一步在SiO2/Si基片上成功构造了基于α-In2Se3(2H)铁电的平面四端器件,详细研究其在各个方向的光响应。结果表明,具有本征结构的α-In2Se3(2H)在相互垂直方向均没有光响应。在器件两端分别施加电压后,α-In2Se3(2H)器件在相互垂直方向均出现了明显的光响应,尤其在接近于易极化轴方向施加电压后,α-In2Se3(2H)器件出现了各向异性光响应。
Anisotropic photoresponse of two-dimensional layered α-In2Se3(2H)ferroelectric materials
The mechanical stripping method prepared the 2H-phase α-In2Se3(α-In2Se3(2H))nanosheets.The struc-ture and ferroelectric properties of the nanosheets were characterized by X-ray diffraction(XRD),Raman spectrosco-py,spherical aberration electron microscopy,and piezoelectric force microscopy.The nanosheets were identified asα-In2Se3(2H)ferroelectric materials with a special structure.Further,a planar four-terminal device based on α-In2Se3(2H)ferroelectricity was successfully constructed on the SiO2/Si substrate,and its photoresponse in all directions was investigated in detail.The results show that α-In2Se3(2H)with intrinsic structure has no photoresponse in both mutually perpendicular directions.After applying voltages at each end of the device,the α-In2Se3(2H)device shows obvious photoresponse in the mutually perpendicular directions.In particular,after utilizing a point voltage close to the direction of the easy polarization axis,the α-In2Se3(2H)device shows an anisotropic photoresponse.

two-dimensional layered α-In2Se3(2H)mechanical stripping methodferroelectricityanisotropic photoresponse

吕宝华、李玉珍

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运城学院应用化学系,运城 044000

运城学院工科实验实训中心,运城 044000

二维层状α-In2Se3(2H) 机械剥离法 铁电性 各向异性光响应

国家自然科学基金山西省高校科技创新项目运城学院博士科研启动项目先进永磁材料与技术省部共建协同创新中心2022年度规划课题

520022322022L477YQ-20230242022-06

2024

无机化学学报
中国化学会

无机化学学报

CSTPCD北大核心
影响因子:0.665
ISSN:1001-4861
年,卷(期):2024.40(10)