无机化学学报2024,Vol.40Issue(10) :1932-1942.DOI:10.11862/CJIC.20240065

ZIF-67衍生Co@C/MoS2纳米复合材料的制备及微波吸收性能

Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS2 nanocomposites

李敏 孟献丰
无机化学学报2024,Vol.40Issue(10) :1932-1942.DOI:10.11862/CJIC.20240065

ZIF-67衍生Co@C/MoS2纳米复合材料的制备及微波吸收性能

Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS2 nanocomposites

李敏 1孟献丰1
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作者信息

  • 1. 江苏大学材料科学与工程学院,镇江 212013
  • 折叠

摘要

通过碳化技术和水热反应相结合成功制备了Co@C/MoS2复合吸波材料.结果表明,ZIF-67的碳化温度和Co@C/MoS2的微观结构对Co@C/MoS2复合材料的吸波性能具有重要影响.Co@C/MoS2的褶皱结构增强了入射波的反射与散射,进而优化了阻抗匹配,提高了材料的电磁波(EMW)吸收性能.当碳化温度为800℃,样品匹配厚度为1.7 mm时,Co@C/MoS2复合材料展现出最佳的吸波性能,最小反射损耗(RLmin)和有效吸收带宽(EAB)分别达到-101.84 dB和7.4 GHz.

Abstract

Co@C/MoS2 wave-absorbing materials were successfully synthesized by the combination of carbonization techniques and hydrothermal reactions.The results indicate that the carbonization temperature of ZIF-67 and the microstructure of Co@C/MoS2 critically influence the wave absorption properties of the Co@C/MoS2 composite mate-rial.The wrinkled structure of Co@C/MoS2 enhances the reflection and scattering of incident waves,thereby optimiz-ing the impedance matching and enhancing the electromagnetic wave(EMW)performance of the material.When the calcination temperature of ZIF-67 was 800 ℃,the minimum reflection loss(RLmin)of-101.84 dB was obtained at the thickness of 1.7 mm,and the corresponding effective absorption bandwidth(EAB)was up to 7.4 GHz.

关键词

纳米复合材料/ZIF-67/Co@C/MoS2/电磁波吸收

Key words

nanocomposite/ZIF-67/Co@C/MoS2/electromagnetic wave absorption

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出版年

2024
无机化学学报
中国化学会

无机化学学报

CSTPCDCSCD北大核心
影响因子:0.665
ISSN:1001-4861
参考文献量31
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