无机盐工业2024,Vol.56Issue(2) :121-126.DOI:10.19964/j.issn.1006-4990.2023-0173

铁尾矿酸浸液制备聚氯化铁的试验研究

Experimental study on preparation of polyferric chloride from iron tailings acid leaching solution

黄涛 黄自力 肖硕 郑洁淼 刘晓峰 吴纪龙
无机盐工业2024,Vol.56Issue(2) :121-126.DOI:10.19964/j.issn.1006-4990.2023-0173

铁尾矿酸浸液制备聚氯化铁的试验研究

Experimental study on preparation of polyferric chloride from iron tailings acid leaching solution

黄涛 1黄自力 1肖硕 1郑洁淼 1刘晓峰 1吴纪龙1
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作者信息

  • 1. 武汉科技大学资源与环境工程学院,冶金矿产资源高效利用与造块湖北省重点试验室,湖北武汉 430081
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摘要

为探索某选矿厂铁尾矿回收利用的新途径,对铁尾矿酸浸液制备聚氯化铁的试验过程进行了研究,并将自制的聚氯化铁应用到高岭土悬浊液的混凝试验中测试产品的絮凝性能.结果表明:聚合的适宜条件为温度为40℃、pH为1.0、聚合时间为3 h,在该条件下合成的聚氯化铁盐基度为20.91%,符合相关标准,影响聚合过程因素的主次顺序依次为聚合温度、pH、聚合时间;混凝的适宜条件为聚氯化铁投加量为250 mg/L、pH为7.0、搅拌时间为3 min、温度为20℃、混凝时间为60 min,在该条件下浊度去除率为95.54%,产品除浊效果良好.

Abstract

In order to explore a new approach to the recovery and utilization of iron tailings from an iron ore dressing plant,the experimental process of preparing polymeric iron chloride from the acid leaching solution of the iron tailings was stud-ied,and the self-made polymeric ferric chloride was applied to the coagulation test of kaolin suspension to test the floccula-tion performance of the product.The experimental results showed that the suitable conditions for polymerization were tem-perature 40℃,pH of 1.0,and polymerization time 3 h.Under these conditions,the alkalinity of synthesized polymerized fer-ric chloride was 20.91%,which met relevant standards,and the primary and secondary ranking of factors affecting the po-lymerization process were polymerization temperature,pH and polymerization time.The suitable conditions for coagulation were the dosage of polymeric ferric chloride of 250 mg/L,pH of 7.0,stirring time of 3 min,temperature of 20℃ and coagula-tion time of 60 min.Under these conditions,the turbidity removal rate was 95.54%,and the product had a good turbidity re-moval effect.

关键词

聚氯化铁/铁尾矿/酸浸液/聚合/混凝

Key words

polyferric chloride/iron tailings/acid leaching solution/polymerization/coagulation

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出版年

2024
无机盐工业
中海油天津化工研究设计院 中国化工学会无机酸碱盐专业委员会

无机盐工业

CSTPCD北大核心
影响因子:0.489
ISSN:1006-4990
参考文献量9
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