首页|钾长石混盐焙烧-浸出提钾过程研究

钾长石混盐焙烧-浸出提钾过程研究

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中国钾盐资源匮乏,而钾长石是一种重要的钾赋存形式.然而,钾长石的开发技术难度大、成本高,至今尚未实现工业化应用.为了解决钾长石开发利用过程中钾提取温度高、浸出率低等问题,该研究选取了贵州铜仁地区钾长石矿为研究对象,探究了钾长石-硫酸钠-碳酸钙混盐的焙烧-浸出过程,考察了钾长石-硫酸钠-碳酸钙的焙烧配比、焙烧温度、焙烧时间、浸取剂浓度等因素对钾长石中钾元素浸出率的影响.实验结果显示,在焙烧体系均匀混合、焙烧温度为800∼900℃、焙烧时间为1 h、m(钾长石)∶m(硫酸钠)∶m(碳酸钙)为(1∶1∶6)~(1∶1∶8)条件下,以质量分数为5%NaOH溶液作为浸取液,钾的浸出率可高达99.79%.该研究提供了一条提高钾长石资源利用效率、解决钾盐资源供应问题的新途径,并为相关工业生产提供了有力的技术支持.
Study on extraction of potassium from K-feldspar by roasting-leaching of mixed salts
Potash resources are scarce in China,and K-feldspar is an important form of potassium occurrence.However,the development of K-feldspar involves significant technical challenges and high costs,and industrial utilization has not yet been achieved.To address issues like high temperatures and low leaching rates during the development and utilization of K-feldspar,the K-feldspar ore from the Guizhou Tongren was selected as research target in this study,and the mixed-salt roasting-leaching process of K-feldspar-sodium sulfate-calcium carbonate was investigated.The effects of factors such as the ratios of K-feldspar-sodium sulfate-calcium carbonate roasting,roasting temperature,roasting time,and leaching reagent on the leaching rate of potassium elements in K-feldspar were explored.The experimental results indicated that under condi-tions of uniform roasting mixture,roasting temperatures within the range of 800∼900℃,roasting time of 1 h,a roasting com-position ratio of ore,sodium sulfate,and calcium carbonate at(1∶1∶6)~(1∶1∶8),and leaching using a mass fraction of 5%NaOH solution,the leaching rate of potassium could reach as high as 99.79%.This study offered a new approach to enhance the efficiency of K-feldspar resource utilization and address potassium resource supply issues.Moreover,it provided robust technical support for relevant industrial production.

K-feldsparcalcinationleaching of potassiumthermodynamic

方小宁、匡飞、刘程琳

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铜仁职业技术学院,贵州铜仁 554300

华东理工大学,国家盐湖资源综合利用工程技术研究中心,上海 200237

钾长石 焙烧 浸出提钾 热力学

黔科合基础项目

[2018]1421

2024

无机盐工业
中海油天津化工研究设计院 中国化工学会无机酸碱盐专业委员会

无机盐工业

CSTPCD北大核心
影响因子:0.489
ISSN:1006-4990
年,卷(期):2024.56(5)
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