无机盐工业2024,Vol.56Issue(8) :110-115.DOI:10.19964/j.issn.1006-4990.2023-0533

磷石膏低温煅烧增白研究

Study on whitening of phosphogypsum by low-temperature calcination

唐雪梅 王美波 徐丽 张旭杰 邰石君 易贤美 刘红娟 潘邻屹
无机盐工业2024,Vol.56Issue(8) :110-115.DOI:10.19964/j.issn.1006-4990.2023-0533

磷石膏低温煅烧增白研究

Study on whitening of phosphogypsum by low-temperature calcination

唐雪梅 1王美波 1徐丽 1张旭杰 1邰石君 1易贤美 1刘红娟 1潘邻屹1
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作者信息

  • 1. 贵州胜威化工新材料研究院有限公司,贵州贵阳 550014
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摘要

基于磷石膏白度对后续磷石膏的大宗利用有至关重要的影响,为了更好地利用磷石膏资源,最大限度地发挥磷石膏的价值,对磷石膏的低温煅烧增白进行了研究.磷石膏经筛分后,在未加添加剂、加入单一添加剂(氯化铵、双氧水、氢氧化钙)、复合添加剂条件下进行煅烧实验.结果表明:单一添加剂中氯化铵的增白效果较好,添加质量分数为1%的氯化铵在460℃下煅烧后,磷石膏白度由68.3%升高至80.5%;当煅烧温度为400℃时,以质量分数为1%的氯化铵与质量分数为2.8%的氢氧化钙作为复合添加剂可以提高磷石膏白度至84.2%,同时在保证磷石膏白度在80.0%以上的条件下,可以将磷石膏煅烧温度降低至350℃.该复合添加剂能有效提高磷石膏白度,降低能耗.

Abstract

Based on the fact that phosphogypsum whiteness had a crucial influence on the subsequent bulk utilization of phosphogypsum,in order to better utilize the phosphogypsum resources,maximize the value of phosphogypsum,and im-prove the phosphogypsum whiteness,the whitening of phosphogypsum by low-temperature calcination was studied.Phospho-gypsum was sieved and calcined under the conditions of no additives,adding single additives(ammonium chloride,hydro-gen peroxide,calcium hydroxide),and composite additives,and the results showed that the whitening effect of ammonium chloride in the single additives was better,and the whiteness of phosphogypsum was increased from 68.3%to 80.5%after adding ammonium chloride with the mass fraction of 1%and calcined at 460℃.At the calcination temperature of 400℃,us-ing ammonium chloride with a mass fraction of 1%and calcium hydroxide with a mass fraction of 2.8%as a composite addi-tive could increase the whiteness of phosphogypsum to 84.2%.In addition,under the condition that the whiteness of phos-phogypsum was above 80.0%,the calcination temperature of phosphogypsum could be reduced to 350℃.This composite ad-ditive could effectively improve the whiteness of phosphogypsum and reduce energy consumption.

关键词

磷石膏/煅烧/增白/复合添加剂

Key words

phosphogypsum/calcination/whitening/composite additive

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基金项目

"钛-磷-硫-铁-钙"全资源循环利用技术创新平台项目(黔科中引地[2022]4019)

工业一铵和钛白副产硫酸亚铁制备电池级磷酸铁技术研究项目(黔科合支撑[2023]一般463)

出版年

2024
无机盐工业
中海油天津化工研究设计院 中国化工学会无机酸碱盐专业委员会

无机盐工业

CSTPCDCSCD北大核心
影响因子:0.489
ISSN:1006-4990
参考文献量9
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