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磷尾矿综合利用现状及研究进展

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中国磷矿资源丰富,但多为中低品位磷矿,需要选矿才能用于化工生产.磷尾矿是磷矿石经选矿产生的磷含量较低的固体废弃物,可以看作中低品位磷尾矿,主要由氧化钙、氧化镁、五氧化二磷、二氧化硅组成,有极大的综合利用潜力.针对磷尾矿的结构、组成成分、物理化学性质综述了磷尾矿综合利用现状及研究进展,详细阐述了磷尾矿在矿区填充、浸取钙镁等有价元素、再选回收磷元素,以及农业、建筑、环保等方面的应用.分析了磷尾矿综合利用过程中面临的问题并对其发展前景进行展望.指出开发新型环保高效的磷尾矿综合利用工艺是磷尾矿利用的发展方向,是磷化工企业和社会的共同需要,符合资源绿色高效利用和可持续发展的基本国策.
Current status and research progress of comprehensive utilization of phosphorus tailings
China is rich in phosphorus ore resources,but most of them are medium and low-grade phosphorus ore,which need to be beneficiated to be used in chemical production.Phosphorus tailings are solid wastes with low phosphorus content produced by beneficiation of phosphorus ore,which can be regarded as low-grade phosphorus tailings,mainly composed of calcium oxide,magnesium oxide,phosphorus pentoxide,silica,and have great potential for comprehensive utilization.In this paper,in view of the structure,composition,and physicochemical properties of phosphorus tailings,the current situation and research progress of the comprehensive utilization of phosphorus tailings were reviewed.The utilization of phosphorus tailings in the filling of the mine,leaching of calcium and magnesium and other valuable elements,re-election and recovery of phosphorus elements,agricultural applications,building applications,environmental protection applications and other as-pects was elaborated in detail.The problems faced in the comprehensive utilization of phosphorus tailings were analyzed and prospects for its development were outlooked.It was pointed out that the development of a new environmentally friendly and efficient comprehensive utilization process of phosphorus tailings was the development direction of phosphorus tailings utili-zation,which was the common need of phosphorus chemical enterprises and society and it was in line with the basic na-tional policy of green and efficient utilization of resources and sustainable development.

phosphorus tailingscomprehensive utilizationgreen environmental protection

王保明、王兴龙、杨英、赵波、化全县、刘咏、刘鹏飞、申博、丁俊祥、汤建伟

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郑州大学生态与环境学院,河南郑州 450001

国家钙镁磷复合肥技术研究推广中心,河南郑州 450001

河南省减污降碳协同工程技术研究中心,河南郑州 450001

郑州大学化工学院,河南郑州 450001

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磷尾矿 综合利用 绿色环保

河南省重点研发专项项目国家自然科学基金面上项目国家重点研发计划项目郑州大学青年骨干教师培养计划项目

231111320502222783812021YFD17009022021ZDGGJS015

2024

无机盐工业
中海油天津化工研究设计院 中国化工学会无机酸碱盐专业委员会

无机盐工业

CSTPCD北大核心
影响因子:0.489
ISSN:1006-4990
年,卷(期):2024.56(10)