物理测试2024,Vol.42Issue(1) :32-36.DOI:10.13228/j.boyuan.issn1001-0777.20230046

成分计算法和差示量热法确定TA24合金相变点

Determination of phase transformation point of TA24 alloy by composition calculating method and differential scanning calorimetry

李春辉 张聪毅 王硕 陈洁明 刘攀 张欣耀
物理测试2024,Vol.42Issue(1) :32-36.DOI:10.13228/j.boyuan.issn1001-0777.20230046

成分计算法和差示量热法确定TA24合金相变点

Determination of phase transformation point of TA24 alloy by composition calculating method and differential scanning calorimetry

李春辉 1张聪毅 1王硕 1陈洁明 1刘攀 2张欣耀3
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作者信息

  • 1. 中国船舶集团有限公司第七二五研究所(洛阳船舶材料研究所),河南洛阳 471023
  • 2. 中国船舶集团有限公司第七二五研究所(洛阳船舶材料研究所),河南洛阳 471023;国家新材料生产应用示范平台(先进海工与高技术船舶材料),河南洛阳 471023;海洋腐蚀与防护全国重点实验室,河南洛阳 471023
  • 3. 中国船舶集团有限公司第七二五研究所(洛阳船舶材料研究所),河南洛阳 471023;海洋腐蚀与防护全国重点实验室,河南洛阳 471023;河南省船舶及海工装备结构材料技术与应用重点实验室,河南洛阳 471023
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摘要

采用成分计算法和差示扫描量热法测试了 4种规格11件TA24近α钛合金试样的β转变温度.成分计算法根据合金元素及杂质对相变温度的贡献率来推算钛合金的β转变温度;差示扫描量热法根据钛合金发生相变时的热量变化测得β转变温度.结果表明:在置信度均取95%的条件下,方法间的偏差为(-1.3±5.8)℃,偏差绝对值为(2.4±3.9)℃.成分计算法和差示扫描量热法的测试结果相符,其偏差介于-6.9~2.4℃,均小于HB 6623.1-1992《钛合金β段变温度测定方法差热分析法》和HB 6623.2-1992《钛合金β转变温度测定方法金相法》规定的实验室内两次平行试验的允许差(±8℃).成分计算法可以作为一种便捷有效的TA24钛合金β转变温度的快速预测方法.

Abstract

The β transformation temperatures of 11 pieces of TA24 near α titanium alloy samples in 4 specifications were measured by composition calculating method and differential scanning calorimetry.In the composition calculating method,the β transformation temperature of titanium alloy was determined according to the contribution rate of alloying elements and impurity elements to the phase transformation temperature.In the differential scanning calorimetry,the β transformation temperature was measured based on the heat change of titanium alloy during phase transition.The results showed that under the condition of 95%confidence,the deviation between methods was(-1.3+5.8)℃,and the absolute value of devia-tion was(2.4±3.9)℃.The measurement results of composition calculating method and differential scanning calorimetry method were consistent,and the deviation was between-6.9 ℃ and 2.4 ℃,which were both less than the allowable de-viation(±8 ℃)of two parallel tests in the laboratory specified by HB 6623.1-1992 and HB 6623.2-1992.The compo-sition calculating method could be used as a convenient and effective method to quickly predict the β transformation temper-ature of TA24 titanium alloy.

关键词

TA24/成分计算法/差示扫描量热法/相变点/Ti75

Key words

TA24/composition calculating method/differential scanning calorimetry/phase transformation point/Ti75

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基金项目

国家新材料生产应用示范平台建设项目(TC180A6MR/2)

出版年

2024
物理测试
中国钢研科技集团有限公司

物理测试

影响因子:0.363
ISSN:1001-0777
参考文献量24
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