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甲醇废热锅炉换热管断裂失效分析

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某工程用S32168甲醇废热锅炉换热管在使用大约一个月时间后不同换热管发生多次开裂泄漏,且开裂位置均处于换热管胀接处.通过分析换热管胀接处宏观及微观断口形貌、微观组织、化学成分及力学性能,发现断口形貌为典型的应力腐蚀断裂和腐蚀疲劳断裂形貌,组织为奥氏体,未发现其他异常组织,成分及力学性能满足相关标准要求.结合废热锅炉管的断裂位置、断口形貌特征、断口表面成分及服役环境,综合分析认为换热管失效主要为应力腐蚀和腐蚀疲劳失效,原因是使用过程中胀管使其内径尺寸大于管内其他位置,容易在此次处形成并存积H2S水溶液腐蚀介质,最终导致换热管于此处开裂及断裂.
Fracture failure analysis of heat exchange tube for methanol waste heat boiler
The cracking and leakage of some heat exchange tubes for S32168 methanol waste heat boiler used in one project were observed after use for about one month.The cracking locations were all at the expansion joints of the heat exchange tubes.The macro and micro fracture morphology,microstructure,chemical composition and mechanical properties of the expansion contact of the heat exchange tube were analyzed.It was found that the fracture morphology was the typical mor-phology of stress corrosion fracture and corrosion fatigue fracture.The microstructure was austenite,and other abnormal structures were not found.The composition and mechanical properties could meet the requirements in related standards.By combining with the fracture position,fracture morphology,chemical composition and service environment,the comprehen-sive analysis indicated that the failure of heat exchange tube was mainly due to stress corrosion and corrosion fatigue failure.The reason was that the expansion of the tube during use made its inner diameter larger than other positions in the tube,which was easy to store corrosive medium of H2S aqueous solution at this place,which finally led to cracking and fracture of heat exchange tube here.

heat exchange tube of waste heat boilerfracturestress corrosioncorrosion fatigue

董莎莎、廉学魁、杨博、李继康、李南、张淑兰

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钢铁研究总院有限公司中心实验室,北京 100081

废热锅炉换热管 断裂 应力腐蚀 腐蚀疲劳

2024

物理测试
中国钢研科技集团有限公司

物理测试

影响因子:0.363
ISSN:1001-0777
年,卷(期):2024.42(2)
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