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非晶铟镓锌氧化物薄膜晶体管制备工艺及性能研究

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本文介绍了利用射频磁控溅射技术在氧化硅衬底上制备非晶氧化铟镓锌(a-IGZO)薄膜,对溅射的薄膜进行了不同条件下的特性分析,制备成 a-IGZO 薄膜晶体管(a-IGZO TFT),并分别研究了溅射气氛、有源层厚度和退火工艺对器件电学性能的影响.实验表明,当使用 50W的溅射功率时,溅射过程中补充氧气,可以填补材料的深能级氧空位缺陷,提高了器件性能.但氧气浓度过大也会造成吸附氧等受主缺陷增多,更易发生载流子的散射,实验中采用氩氧比为 Ar∶O2=24∶1.2 的条件器件性能较好.其次,当有源层厚度控制在 40~50nm时,器件性能较好,且 40nm 的薄膜性质更佳.最后,高温退火工艺可以改善薄膜的缺陷,消除薄膜内部原有应力.相比氮气退火条件,将薄膜在空气下退火可以实现更好的电学特性,将 40nm 的薄膜在空气下 400℃退火30min,a-IGZO TFT 的性能达到最佳,其迁移率为 15.43cm2/(V·s),阈值电压为13.09V,电流开关比为 7.3×108,为将来制备晶圆级的高迁移a-IGZO TFT奠定了基础.
STUDY ON FABRICATION PROCESS AND PROPERTIES OF AMORPHOUS INGAZNO THIN FILM TRANSISTOR
The present study reports on the fabrication of amorphous InGaZnO(a-IGZO)thin films on silicon oxide substrates using radio-frequency magnetron sputtering technique,and investigates their characteristics under different conditions.Subsequently,a-IGZO thin-film transistors(a-IGZO TFT)were prepared and their electrical properties were studied in rela-tion to the effects of sputtering atmosphere,active layer thickness,and annealing process.The experimental findings demonstrate that,when using a sputtering power of 50 W,the per-formance of the device can be improved by introducing supplemental oxygen into the sputte-ring process,which effectively mitigates the deep-level oxygen vacancy defects in the materi-al.However,an excessive concentration of oxygen may give rise to an increase in the number of acceptor defects,such as adsorbed oxygen,which promotes carrier scattering.Based on our investigation,we determined that the device exhibited optimal performance when the argon-oxygen ratio was maintained at Ar∶O2=24∶1.2.Secondly,optimal performance of the de-vice is achieved by controlling the thickness of the active layer within the range of 40~50nm,with the film properties peaking at a thickness of 40nm.Finally,the application of high-tem-perature annealing process serves to alleviate the defects of the film,while also effectively eliminating any internal stresses that may exist within the film.In comparison with nitrogen annealing conditions,annealing a-IGZO films under an air environment leads to superior elec-trical properties.Specifically,annealing a 40nm-thick film at 400℃for 30 minutes in air re-sulted in the optimal performance of the a-IGZO TFT device,with a recorded mobility of 15.43cm2/(V·s),a threshold voltage of 13.09 V,and a current switching ratio of 7.3×108.These findings establish a solid foundation for future endeavors towards the preparation of wa-fer-level high-mobility a-IGZO TFTs.

IGZOThin film transistorsmagnetron sputteringactive layer thicknessan-nealing

刘丽、吕腾博、刘嘉乐、程乾、王小力

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沈阳大学师范学院,辽宁 沈阳 110003

西安交通大学微电子学院,陕西 西安 710049

西安交通大学物理学院,陕西 西安 710049

铟镓锌氧化物 薄膜晶体管 磁控溅射 有源层厚度 退火

陕西省重点研发计划项目

2023-YBSF-407

2024

物理与工程
清华大学

物理与工程

CSTPCD
影响因子:0.63
ISSN:1009-7104
年,卷(期):2024.34(3)
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