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高环多环芳烃污染土壤氧化修复

Oxidation Remediation of High-molecular Weight PAHs Contaminated Soil

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多环芳烃类污染物中, 高环多环芳烃分子量大, 结构稳定, 难以去除.研究以京津冀地区某污染土壤作为研究对象, 针对苯并 (a) 蒽、苯并 (b) 荧蒽、苯并 (a) 芘、茚并 (1, 2, 3-cd) 芘、二苯并 (a, h) 蒽五种高环多环芳烃, 使用了次氯酸钠、过氧化氢、过硫酸钠、高锰酸钾四种试剂进行氧化实验, 并针对不同氧化剂, 探索了加强其氧化能力方法, 实验结果显示, 经亚铁离子活化的过硫酸钠 (过硫酸钠10 g/L, 硫酸亚铁1g/L, 柠檬酸0.1g/L) 对高环多环芳烃具有相对较好的处理结果.文中结论可为高环多环芳烃氧化处理提供借鉴.
High-molecular Weight polycyclic aromatic hydrocarbons which have high molecular weight and stable structure are difficult to be removed. In this study, using different oxidations to oxidate the High-molecular Weight polycyclic aromatic hydrocarbons include Ba A, Bb F, Ba P, IPY, DBA, in soil samples which are taken from contaminated soil in Jing-jin-ji district. The result show that typical oxidations including sodium hypochlorite, hydrogen peroxide, sodium persulfate, Potassium Permanganate have different effects in High-molecular Weight polycyclic aromatic hydrocarbons removal. Then the method to strengthen its ability of oxidation is explored. The result show that the PAHs removal rate have improved though the oxidation advanced. The suitable concentration of advanced oxidation is sodium persulfate: 10 g/L; ferrous sulfate: 1 g/L, citric acid: 0. 1 g/L. The conclusion can be used as a reference for the oxidation treatment of High-molecular Weight polycyclic aromatic hydrocarbons.

high-molecular weight PAHsindustrial pollution sitesoxidationremediation

何达、苏志龙、侯国凤

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天津市环境保护技术开发中心设计所, 天津 300110

高环多环芳烃 工业污染场地 氧化剂 修复

2018

污染防治技术
中国环境科学学会 江苏省环境科学学会

污染防治技术

ISSN:
年,卷(期):2018.31(1)
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