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螯合剂对污泥中重金属Mn和Zn活化效果

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植物提取技术已经成为当前去除污泥中重金属最具有发展前景的方法.然而污泥中大部分重金属的有效形态含量比较低, 严重阻碍了植物的吸收.为解决上述问题文中将利用BCR四步提取法研究EDTA-Na2、酒石酸两种螯合剂的添加对于Mn、Zn金属形态的影响及其形态的转变情况.结果表明, 原污泥中Mn、Zn的弱酸提取态含量比较低, EDTA-Na2、酒石酸添加后, 污泥中Mn、Zn的重金属形态均发生不同程度的变化, 重金属Mn、Zn酸可提取态含量随着螯合剂浓度的增加而增加, 随后逐渐达到稳定且螯合剂添加的浓度和Mn、Zn的有效形态相关性明显.
Chelating agents on activation effect of heavy metals in sludge Mn and Zn
Plant extraction technology has become the most promising method for removing heavy metals from sludge. However, most available form content of heavy metals in sewage sludge is low, which seriously hinders the absorption of plants. In this paper, the four-step of BCR was used to study the effects of EDTA-Na2 and tartaric acid on the morphology of Mn and Zn and the change of their morphology. The results show that Mn and Zn in the raw sludge acid extractable content are relatively low. After EDTA-Na2 and tartaric acid were added, the heavy metal forms of Mn and Zn in the sludge were changed, the heavy metal Mn and Zn acid extractable content increased with the increasing concentration of the chelating agent and then tends to be stable. The concentration of chelating agent is significantly correlated with Mn and Zn.

heavy metal chelating agenteffective formthe activation of heavy metals

汪佛松

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江苏江南环境工程设计院有限公司, 江苏 南京 210000

污泥 螯合剂 重金属有效形态 重金属活化

2018

污染防治技术
中国环境科学学会 江苏省环境科学学会

污染防治技术

ISSN:
年,卷(期):2018.31(5)
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