西安工业大学学报2024,Vol.44Issue(4) :405-412.DOI:10.16185/j.jxatu.edu.cn.2024.04.101

铝-水反应制氢副产物AlO(OH)的回收及阻燃利用

Recovery and Flame Retardant Utilization of AlO(OH)from Hydrogen Production by Al/H2O Reaction

张建斌 张宝东 徐建林
西安工业大学学报2024,Vol.44Issue(4) :405-412.DOI:10.16185/j.jxatu.edu.cn.2024.04.101

铝-水反应制氢副产物AlO(OH)的回收及阻燃利用

Recovery and Flame Retardant Utilization of AlO(OH)from Hydrogen Production by Al/H2O Reaction

张建斌 1张宝东 1徐建林1
扫码查看

作者信息

  • 1. 兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室,兰州 730050
  • 折叠

摘要

针对制氢用活性铝合金水解产物中除气态H2外,还有固态副产物AlO(OH)等的回收和再利用问题.以自制AlO(OH)阻燃添加剂,与聚丙烯(PP)熔融共混制备AlO(OH)/PP复合材料.采用极限氧指数测定仪、热重分析仪、差示扫描量热仪对AlO(OH)/PP复合材料的阻燃性能、热稳定性和结晶行为进行研究.结果表明:随着AlO(OH)从0增加到25%,极限氧指数(LOI)和热稳定性提升,熔滴的滴落得到抑制.AlO(OH)为25%时复合材料的LOI较纯PP提升了29.2%,复合材料结晶峰值温度增加、结晶度下降,自制AlO(OH)具有阻燃效果.

Abstract

The study focuses on the recycling and reuse of solid by-products in addition to gaseous H2 in the hydrolysis products of activated aluminium alloys for hydrogen production.A home-made AlO(OH)flame retardant was melt-blended with polypropylene(PP)to produce AlO(OH)/PP composites.Their flame retardancy,thermal stability and crystallisation behaviour were investigated with a limiting oxygen index tester,a thermogravimetric analyzer and a differential scanning calorimeter.The results show that as the mass percentage of AlO(OH)increases from zero to 25%,the limiting oxygen index(LOI)and thermal stability increase and the dropping of molten drops is suppressed.The LOI of the composites at 25%AlO(OH)is improved by 29.2%compared to pure PP,and the peak crystallization temperature of the composites increase and the crystallinity decreases,suggesting that the home-made AlO(OH)performs well as a flame retardant.

关键词

AlO(OH)/聚丙烯/阻燃/热稳定性

Key words

AlO(OH)/polypropylene/flame retardant/thermal stability

引用本文复制引用

出版年

2024
西安工业大学学报
西安工业大学

西安工业大学学报

CSTPCDCHSSCD
影响因子:0.381
ISSN:1673-9965
段落导航相关论文