西安工业大学学报2024,Vol.44Issue(4) :413-423.DOI:10.16185/j.jxatu.edu.cn.2024.04.102

Cr3C2+Ti复合改性激光熔覆Fe-0.3C-15Cr-1Ni合金的组织与性能

Microstructure and Properties of Cr3C2+Ti Composite Modified Laser Clad Fe-0.3C-15Cr-1Ni Alloy

胡德荣 郭铁明 张瑞华 南雪丽 董康 尹燕 易湘斌
西安工业大学学报2024,Vol.44Issue(4) :413-423.DOI:10.16185/j.jxatu.edu.cn.2024.04.102

Cr3C2+Ti复合改性激光熔覆Fe-0.3C-15Cr-1Ni合金的组织与性能

Microstructure and Properties of Cr3C2+Ti Composite Modified Laser Clad Fe-0.3C-15Cr-1Ni Alloy

胡德荣 1郭铁明 1张瑞华 2南雪丽 1董康 1尹燕 1易湘斌3
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作者信息

  • 1. 兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室,兰州 730050
  • 2. 阳江市五金刀剪产业技术研究院,阳江 529533
  • 3. 甘肃省精密加工技术及装备工程研究中心,兰州 730050
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摘要

为了改善Fe-0.3C-15Cr-1Ni合金涂层的硬度和耐蚀性能.采用激光熔覆技术在3Cr13不锈钢基体表面熔覆添加不同含量(Cr3C2+Ti)(0,0.5%,1%,2%)原位合成含有TiC的不锈钢基高硬度耐蚀涂层,利用金相显微镜(OM)、扫描电子显微镜(SEM)、X射线衍射仪(XRD)、显微硬度仪、电化学工作站等设备研究不同含量(Cr3C2+Ti)对熔覆层的微观结构、相组成、硬度分布及耐蚀性能的影响.结果表明:熔覆层与3Cr13不锈钢基体间界面冶金结合良好.加入(Cr3C2+Ti)后熔覆层的树枝晶和柱状晶转变为胞状晶和等轴晶;碳化物由鱼骨状和块状转变为棒状和颗粒状,且数量减少,其类型由低碳型碳化物向高碳型碳化物转变.随着(Cr3C2+Ti)含量的提高,熔覆层的硬度先升高后降低,点蚀电位先升高后降低,钝化区宽度先增大后减小.结果表明在Fe-0.3C-15Cr-1Ni合金粉末中添加(Cr3C2+Ti)可显著提高马氏体不锈钢基涂层硬度和耐蚀性能,当(Cr3C2+Ti)含量为0.5%时,熔覆层的综合性能最好.

Abstract

The study aims to improve the hardness and corrosion resistance of Fe-0.3C-15Cr-1Ni alloy coatings.Stainless steel-based and TiC-containing coatings with high hardness and corrosion resistance were in-situ synthesized by the laser cladding technique on the surface of 3Cr13 stainless steel substrate with different contents of(Cr3C2+Ti)(0,0.5%,1%,2%).A Metallographic microscope(OM),a scanning electron microscope(SEM),an X-ray diffractometer(XRD),a microhardness tester,an electrochemical workstation and other equipment were used to study the effects of different contents of(Cr3C2+Ti)on the microstructure,phase composition,hardness distribution and corrosion resistance of the clad layers.The results show that the interfacial metallurgical bonding between the clad layer and the 3Cr13 stainless steel matrix is good.With(Cr3C2+Ti)added,the dendrites and columnar crystals of the clad layer were changed to cytosolic and equiaxed crystals;the carbides were changed from herringbone and massive to rod and granular,from low-carbon carbides to high-carbon carbides and declined in number.With the increase of(Cr3C2+Ti)content,the hardness of the clad layer,the pitting potential and the width of the passivation zone increase first and then decrease.The results show that the addition of(Cr3C2+Ti)to Fe-0.3C-15Cr-1Ni alloy powder can significantly improve the hardness and corrosion resistance of the martensitic stainless steel-based coatings.The overall performance of the clad layer is the best when the(Cr3C2+Ti)content is 0.5%.

关键词

激光熔覆/原位合成/TiC/微观组织/显微硬度/耐蚀性能

Key words

laser cladding/in-situ synthesis/TiC/microstructure/microhardness/corrosion resistance

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出版年

2024
西安工业大学学报
西安工业大学

西安工业大学学报

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影响因子:0.381
ISSN:1673-9965
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