首页|静电纺SiO2/PVDF隔膜的制备及性能

静电纺SiO2/PVDF隔膜的制备及性能

Preparation and Properties of SiO2/PVDF Membranes by Electrospinning

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由于静电纺丝纤维具有比表面积较高、孔隙率较高和连通的三维网状结构等优点,在锂离子电池领域的应用前景广阔.为提高聚偏氟乙烯(PVDF)纤维的亲水性和吸液率,将纳米SiO2和PVDF均匀分散在N,N-二甲基甲酰胺中作为前驱体溶液,通过静电纺丝技术制备SiO2/PVDF复合纤维膜,并对制备所得的复合纤维膜的微观形貌、物相结构进行表征分析,对其力学性能、润湿性进行测试.结果表明:SiO2/PVDF复合膜中的纤维随机分布,其直径在0.21~0.28μm之间,纤维表面光滑;SiO2/PVDF复合纤维膜的亲水性随着SiO2含量的增大而提高;当SiO2含量为5(质量分数,%)时,SiO2/PVDF复合纤维膜的性能良好,其拉伸强度为27.5 MPa,断裂延伸率为36.32%,吸液率为369.45%,孔隙率为85.67%,满足作为锂离子电池隔膜使用的要求.
Electrospinning fibers,with the advantages of high specific surface area,high porosity and inter connected three-dimensional network structure,has a promising application in the field of lithium-ion batteries.To enhance the hydrophilicity and liquid absorption rate of PVDF(polyvinyli-dene fluoride)fibers,nano SiO2 and PVDF are uniformly dispersed in N,N-dimethylformamide as a precursor solution.SiO2/PVDF composite fiber membranes are prepared using the electrospin-ning technique.The microstructure and phase structure of the resulting composite fiber mem-branes are characterized and analyzed,and their mechanical properties and wettability are tested.The results show that the fibers in the SiO2/PVDF composite membrane are randomly distributed with diameters ranging from 0.21 μm to 0.28 and have smooth surfaces.The hydrophilicity of the SiO2/PVDF composite fiber membrane increases with the increase of SiO2 content.When the SiO2 content is 5%(mass fraction),the SiO2/PVDF composite fiber membrane exhibits good performance,with a tensile strength of 27.5 MPa,an elongation at break of 36.32%,a liquid absorption rate of 369.45%,and a porosity of 85.67%,meeting the requirements for use as a membrane in lithium-ion batteries.

PVDFnano SiO2electrospinning fibersbattery separatorwettability

何凤利、权爽、王熙、何光磊

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西安航空学院材料工程学院,西安 710077

河南平原同力建材有限公司,河南新乡 453700

PVDF 纳米SiO2 静电纺丝 电池隔膜 润湿性

2024

西安航空学院学报
西安航空技术高等专科学校

西安航空学院学报

影响因子:0.351
ISSN:1008-9233
年,卷(期):2024.42(5)