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煤制兰炭过程中挥发性有机污染物和臭氧协同处理机理

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为探究低温等离子体联合催化剂载体协同处理煤制兰炭过程中产生的挥发性有机污染物及臭氧,以二甲苯作为目标污染物,选取γ-氧化铝小球为催化剂载体,考察功率、氧通量、二甲苯初始浓度、催化剂载体用量等因素对挥发性有机污染物和臭氧协同处理效果的影响。结果表明:低温等离子体放电功率越大,二甲苯的脱除效果越好;在放电功率为70 W、氧通量为15%、初始浓度为600 × 10-6时,二甲苯的去除率为64。41%,此时臭氧的产生量为125。21 × 10-6,综合考量在该性能下的协同处理效率最高;在最优低温等离子体性能的条件下,γ-氧化铝载体粒径越小,二甲苯的去除效率越高,协同处理效果最佳,二甲苯总去除率最高可达73。93%,臭氧抑制率最高为66。45%。γ-氧化铝载体对低温等离子体协同处理挥发性有机污染物与臭氧具有一定的促进作用。研究成果可为协同处理挥发性有机污染物提供有效的参考。
Synergistic treatment mechanism of volatile organic pollutants and ozone in coal-based semi-coke process
In order to explore the synergistic treatment of volatile organic pollutants and ozone produced in coal-based semi-coke process by low temperature plasma combined with catalyst carrier,xylene was used as the target pollutant,and γ-alumina sphere was selected as the catalyst carrier,the effects of power,oxygen flux,initial concentration of xylene and catalyst carrier dosage on the synergistic treat-ment of volatile organic pollutants and ozone were investigated.The results show that the greater the power of low temperature plasma discharge,the better the removal effects of xylene.When the discharge power was 70 W,the oxygen flux was 15%,and the initial concentration was 600 × 10-6,the removal rate of xylene reached 64.41%,and the ozone production was only 125.21 × 10-6;the synergistic treatment efficiency was the highest for this performance.Under the condition of optimal low tempera-ture plasma performance,the smaller the particle size of γ-alumina carrier,the higher the removal effi-ciency of xylene,which is the best synergistic treatment effect.The total removal rate of xylene could reach 73.93%,and the highest ozone inhibition rate was 66.45%.Therefore,γ-alumina carrier has a certain promoting effect on the synergistic treatment of volatile organic pollutants and ozone by low tem-perature plasma.The research results can provide an effective reference for the synergistic treatment of volatile organic pollutants.

semi-cokelow temperature plasmavolatile organic pollutantsozone

张蕾、陈雅、贾阳、黄鹏程

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西安科技大学地质与环境学院,陕西西安 710054

陕西煤田地质集团有限公司 自然资源部煤炭资源勘查与综合利用重点实验室,陕西西安 710021

西安理工大学西北干旱区生态水力学国家重点实验室,陕西西安 710048

宁夏回族自治区煤炭地质局,宁夏银川 750002

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兰炭 低温等离子体 挥发性有机污染物 臭氧

陕西省技术创新引导专项基金陕西省自然科学基础研究计划项目陕西省煤炭绿色开发地质保障重点实验室项目宁夏回族自治区重点研发计划项目

2022QFY06-042019JL-01DZBZ2021Z-012023BEG02058

2024

西安科技大学学报
西安科技大学

西安科技大学学报

CSTPCD北大核心
影响因子:1.154
ISSN:1672-9315
年,卷(期):2024.44(1)
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