西安科技大学学报2024,Vol.44Issue(2) :226-235.DOI:10.13800/j.cnki.xakjdxxb.2024.0203

改性蒙脱土/硼酸锌/硅橡胶泡沫复合材料的阻燃性能及热降解动力学

Flame retardant properties and thermal degradation kinetics of modified montmorillonite/zinc borate/silicone rubber foam composite

刘博 冀贤 王春雨 梁文昊 张馨 丁东杰
西安科技大学学报2024,Vol.44Issue(2) :226-235.DOI:10.13800/j.cnki.xakjdxxb.2024.0203

改性蒙脱土/硼酸锌/硅橡胶泡沫复合材料的阻燃性能及热降解动力学

Flame retardant properties and thermal degradation kinetics of modified montmorillonite/zinc borate/silicone rubber foam composite

刘博 1冀贤 1王春雨 2梁文昊 1张馨 1丁东杰1
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作者信息

  • 1. 西安科技大学安全科学与工程学院,陕西西安 710054
  • 2. 中国建研院检测中心有限公司,北京 100083
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摘要

为提高硅橡胶泡沫(SRF)阻燃性能,将有机改性后的蒙脱土(MMT)和硼酸锌(ZB)作为阻燃剂添加到硅橡胶泡沫中,采用室温硫化法制备了有机改性蒙脱土(OMMT)/硼酸锌(ZB)/硅橡胶泡沫(SRF)复合材料,通过极限氧指数(LOI)、水平-垂直燃烧试验(UL-94)、烟密度测试研究了 SRF复合材料的阻燃性能,通过热重-红外联用分析其热稳定性以及热解气体成分,并采用非等温法开展了复合材料热降解热动力学分析.结果表明:添加2wt%的OMMT和1wt%的ZB时复合材料的LOI最高达到29.5%,比纯SRF提高了 11.3%;最大烟密度(MSD)和烟密度等级(SDR)较纯SRF分别降低了 32.9%、34.1%,延缓了 SRF复合材料的热分解进程,残炭量提高;2wt%OMMT/1wt%ZB/SRF复合材料的活化能在热解后期明显提高,说明OMMT和ZB复配可以有效协同提高SRF复合材料的阻燃抑烟性能,阻燃作用主要体现在热解第2阶段.

Abstract

In order to improve the flame retardant performance of silicone rubber foam,organically mod-ified montmorillonite and zinc borate were added as flame retardants to silicone rubber foam,and organ-ically modified montmorillonite/zinc borate/silicone rubber foam composites were prepared by room temperature vulcanization method,and the flame retardant properties of SRF composites were studied by limiting oxygen index,horizontal-vertical combustion test and smoke density test.The thermal stabil-ity and pyrolysis gas composition of the composites were studied by thermogravimetry-infrared analysis,and the thermodynamic analysis of thermal degradation of composites was carried out by non-isothermal method.The results show that the LOI of the composites reaches a maximum of 29.5%when 2wt%OMMT and 1wt%ZB are added,which is 11.3%higher than that of pure SRF.The maximum smoke density and smoke density grade are reduced by 32.9%and 34.1%respectively compared with pure SRF,which delays the thermal decomposition process of SRF composites and increass the amount of carbon residue.The activation energy of 2wt%OMMT/1 wt%ZB/SRF composites is significantly im-proved in the later stage of pyrolysis,indicating that the combination of OMMT and ZB can effectively improve the flame retardant and smoke suppression properties of SRF composites,and the flame retard-ant effect is mainly reflected in the later stage of pyrolysis.

关键词

改性蒙脱土/硼酸锌/阻燃/硅橡胶泡沫/热动力学

Key words

modified montmorillonite/zinc borate/flame retardant/silicone rubber foam/thermodynam-ics

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基金项目

国家自然科学基金(51904233)

国家自然科学基金(52074218)

陕西省科技创新团队项目(2020TD-021)

出版年

2024
西安科技大学学报
西安科技大学

西安科技大学学报

CSTPCD北大核心
影响因子:1.154
ISSN:1672-9315
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参考文献量30
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