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黄陵矿区西北部薄煤层孔渗特点与CO2封存潜力

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为研究CO2在薄煤层的封存潜力与主控因素,以陕西黄陵矿区西北部薄煤层为例,运用压汞、液氮、核磁共振、CO2等温吸附等试验方法,探讨宏观煤岩类型制约下的煤储层孔裂隙系统与渗透性发育特点,揭示不同含水状态下CO2吸附能力差异及其内在原因。结果表明:半亮煤样品镜质组含量高,各级孔、裂隙系统发育且连通性好;半暗煤样品惰质组与矿物质含量高,孔隙以微、小孔为主,孔隙连通性差;半亮煤样品孔渗条件好于半暗煤样品,为CO2注入提供了有利条件;煤层总体具有较强的CO2吸附能力,干燥条件下,半亮煤样品对CO2 的吸附量大于半暗煤样品,而平衡水条件下,吸附量关系发生反转,源于宏观煤岩类型制约下的润湿性差异;亲水性更强的半亮煤样品在平衡水条件下具有更高的含水率,减少了CO2的吸附空间并堵塞吼道,从而降低了其对CO2的吸附能力;薄煤层条件下CO2封存选址应优先考虑光亮组分含量高、水分含量低的吸附储集优势区域;煤岩组分(类型)与水分含量将是薄煤层条件下CO2封存潜力评价的重要基础参数。
Porous characteristics and CO2 storage potential of a thin coal seam in the northwest Huangling mining area
To study the storage potential and main controlling factors of CO2 in thin coal seams,a thin coal seam in the northwest of the Huangling mining area in the Shaanxi Province was taken as an exam-ple,and such experimental methods as mercury intrusion,liquid nitrogen,nuclear magnetic resonance,and CO2 isothermal adsorption were applied to explore the characteristics of pore fracture system and permeability of coal reservoir under the controls of macroscopic coal rock types,and to reveal the differ-ence of CO2 adsorption capacity in different water-bearing states and its internal reasons.The results show that the vitrinite content of semi-bright coal sample is high,and the pore and fracture systems at all levels are developed and well connected;The content of inertinite and minerals in semi-dark coal sample is high,and the pores are mainly micro-pores,with poor pore connectivity;The porosity and per-meability conditions of semi-bright coal sample are better than those of semi-dark coal sample,provi-ding convenient conditions for CO2 injection.The coal seam has a strong CO2 adsorption capacity.Un-der dry conditions,the CO2 adsorption capacity of semi-bright coal sample is greater than that of semi-dark coal sample,while under equilibrium water conditions,the adsorption capacity relationship is re-versed,which is due to the wettability difference under the controls of macroscopic coal rock types.Semi-bright coal sample with stronger wettability has higher water content under the conditions of equi-librium water state,which will reduce CO2 adsorption space and block roaring channels,thereby reduc-ing its CO2 adsorption capacity.The conclusions indicate that:CO2 storage sites under thin coal seam conditions should prioritize adsorption and storage advantage areas with high bright component content and low moisture content to compensate;The coal rock composition(type)and moisture content of coal will be important basic parameters for evaluating the potential of CO2 storage in thin coal seams.

CO2 storagethin coal seamadsorptionpore and fracturemacroscopic coal rock type

贺炳伟、薛海涛、周明明、赵强、杨先阔、郭晨

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延安车村煤业(集团)有限责任公司,陕西 延安 717300

富县矿业开发有限公司 芦村二号煤矿分公司,陕西 延安 727500

西安科技大学 地质与环境学院,陕西 西安 710054

CO2封存 薄煤层 吸附 孔裂隙 宏观煤岩类型

2024

西安科技大学学报
西安科技大学

西安科技大学学报

CSTPCD北大核心
影响因子:1.154
ISSN:1672-9315
年,卷(期):2024.44(6)